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    • 1. 发明专利
    • DE69212289D1
    • 1996-08-22
    • DE69212289
    • 1992-12-11
    • KUNO TADAHIKOHOSOKAWA JUN ICHITOKO ABANSU CO
    • KUNO TADAHIKO
    • B01D21/01C01F7/68C01G49/00C02F1/00C02F1/50C02F1/52
    • A clarificant of wastewater comprises an aqueous solution of a polynuclear complex salt comprising sulfates of a plurality of the metals K, Fe, Ca, Na, Mg and Al, e.g. containing per 1000 ml of water 0.78-5.63 g K ions, 6.00-72.60 g Fe , 0.12-1.20 g Ca , 0.10-1.00 g Na , 6.56-19-70 g Mg , 6.21-35.00 g Al and 106.08-463.77 g SO4 ions. It is prepared by heating, e.g. at 100 DEG - 190 DEG C and a pressure of 1 to 10.0 kgf/cm , isochorically an aqueous solution containing the said mixture of sulfates, e.g. containing 0.02-0.08 M K , 0.11-1.31 M Fe , 0.003-0.30 M Ca , 0.004-0.40 M Na , 0.27-0.81 M Mg and 0.370-1.300 Al . The solution is added to and rapidly stirred with wastewater to adjust its pH to 4-5 and an alkali, e.g. Ca(OH)2, is added until the pH is 6-8.5, so as to flocculate nearly all the suspended contaminants and the floc is removed. The wastewater treated can be industrial or domestic effluent water or natural water, and there is thus obtained a reduction in biological and chemical oxygen demands and in suspended solids.
    • 2. 发明公开
    • Metallic sulfates as wastewater clarificant and their preparation
    • Metall sulfate als Flockungsmittelfürdie Abwasserreinigung und ihre Herstellung。
    • EP0546850A1
    • 1993-06-16
    • EP92311334.4
    • 1992-12-11
    • Kuno, TadahikoHosokawa, Jun-ichiTOKO ABANSU CO., LTD.
    • Kuno, Tadahiko
    • C02F1/52
    • C02F1/5236C01F7/68C01G49/009
    • A clarificant of wastewater comprises an aqueous solution of a polynuclear complex salt comprising sulfates of a plurality of the metals K, Fe, Ca, Na, Mg and Al, e.g. containing per 1000 ml of water 0.78-5.63 g K⁺ ions, 6.00-72.60 g Fe⁺⁺, 0.12-1.20 g Ca⁺⁺, 0.10-1.00 g Na⁺, 6.56-19-70 g Mg⁺⁺, 6.21-35.00 g Al⁺⁺⁺ and 106.08-463.77 g SO₄⁻⁻ ions.
      It is prepared by heating, e.g. at 100° - 190°C and a pressure of 1 to 10.0 kgf/cm², isochorically an aqueous solution containing the said mixture of sulfates, e.g. containing 0.02-0.08 M K⁺, 0.11-1.31 M Fe⁺⁺, 0.003-0.30 M Ca⁺⁺, 0.004-0.40 M Na⁺, 0.27-0.81 M Mg⁺⁺ and 0.370-1.300 Al⁺⁺⁺.
      The solution is added to and rapidly stirred with wastewater to adjust its pH to 4-5 and an alkali, e.g. Ca(OH)₂, is added until the pH is 6-8.5, so as to flocculate nearly all the suspended contaminants and the floc is removed.
      The wastewater treated can be industrial or domestic effluent water or natural water, and there is thus obtained a reduction in biological and chemical oxygen demands and in suspended solids.
    • 显着的废水包括多金属络合盐的水溶液,其包含多种金属K,Fe,Ca,Na,Mg和Al的硫酸盐,例如。 含有每1000ml水0.78-5.63g K +,6.00-72.60g Fe +,0.12-1.20g Ca ++,0.10-1.00g Na +,6.56 -19-70g Mg +,6.21-35.00g Al + +和106.08-463.77g SO4 - - 离子。 它通过加热,例如 在100°-190℃和1至10.0kgf / cm 2的压力下,等离子地加入含有所述硫酸盐混合物的水溶液,例如, 含有0.02-0.08Mg +,0.11-1.31M Fe +,0.003-0.30M Ca ++,0.004-0.40M Na +,0.27-0.81M Mg + <+>和0.370-1.300的Al + + + +。 将溶液加入并与废水快速搅拌以将其pH调节至4-5,加入碱,例如水。 加入Ca(OH)2直到pH为6-8.5,以便将几乎所有悬浮的污染物絮凝,并除去絮凝物。 经处理的废水可以是工业或家庭废水或天然水,从而获得生物和化学需氧量以及悬浮固体的降低。
    • 3. 发明专利
    • DE69212289T2
    • 1997-02-20
    • DE69212289
    • 1992-12-11
    • KUNO TADAHIKOHOSOKAWA JUN ICHITOKO ABANSU CO
    • KUNO TADAHIKO
    • B01D21/01C01F7/68C01G49/00C02F1/00C02F1/50C02F1/52
    • A clarificant of wastewater comprises an aqueous solution of a polynuclear complex salt comprising sulfates of a plurality of the metals K, Fe, Ca, Na, Mg and Al, e.g. containing per 1000 ml of water 0.78-5.63 g K ions, 6.00-72.60 g Fe , 0.12-1.20 g Ca , 0.10-1.00 g Na , 6.56-19-70 g Mg , 6.21-35.00 g Al and 106.08-463.77 g SO4 ions. It is prepared by heating, e.g. at 100 DEG - 190 DEG C and a pressure of 1 to 10.0 kgf/cm , isochorically an aqueous solution containing the said mixture of sulfates, e.g. containing 0.02-0.08 M K , 0.11-1.31 M Fe , 0.003-0.30 M Ca , 0.004-0.40 M Na , 0.27-0.81 M Mg and 0.370-1.300 Al . The solution is added to and rapidly stirred with wastewater to adjust its pH to 4-5 and an alkali, e.g. Ca(OH)2, is added until the pH is 6-8.5, so as to flocculate nearly all the suspended contaminants and the floc is removed. The wastewater treated can be industrial or domestic effluent water or natural water, and there is thus obtained a reduction in biological and chemical oxygen demands and in suspended solids.