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1. 发明申请

WO2004045759A2 POROUS POLYMERIC COORDINATION COMPOUNDS 审中-公开
标题翻译：多孔聚合物协同化合物
公开(公告)号：WO2004045759A2
公开(公告)日：2004-06-03
申请号：PCT/US2003/037269
申请日：2003-11-20
申请人： RUTGERS, THE STATE UNIVERSITY , LI, Jing , PAN, Long , HUANG, Xiaoying
发明人： LI, Jing , PAN, Long , HUANG, Xiaoying
IPC分类号： B01J
CPC分类号： C07F15/065
摘要： The present invention describes three-dimensional porous coordination compounds, a method of making the compounds, and a method of using the compounds to contain reactants in a reaction, said compounds characterized by a plurality of sheets comprising a two-dimensional array of repeating structural units comprising at least one transition metal, one polyfunctional ligand and one exodentate ligand wherein: (1) at least one binding member of each said polyfunctional ligand is coordinated to transition metal atoms in two different repeating structural units within one sheet; (2) said binding sites of each exodentate bridging ligand are coordinated to transition metal atoms in a each of two adjacent sheets, and (3) the ligands of the three-dimensional polymeric compound define channels and pores of molecular size throughout the structure of the compound.
摘要翻译：本发明描述了三维多孔配位化合物，一种制备该化合物的方法，以及一种在反应中使用该化合物含有反应物的方法，所述化合物的特征在于包括重复结构单元的二维阵列包括至少一种过渡金属，一种多官能配体和一种外分子配体，其中：（1）每个所述多官能配体的至少一个结合成员与一片中两个不同重复结构单元中的过渡金属原子配位; （2）每个外部桥接配体的所述结合位点与两个相邻片段中的每一个中的过渡金属原子配位，并且（3）三维聚合物的配体在整个结构中定义分子大小的通道和孔复合。

2. 发明申请

WO02083774A3 HYBRID NANOSTRUCTURED MATERIALS BASED ON II-VI SEMICONDUCTORS 审中-公开
标题翻译：基于II-VI半导体的混合纳米结构材料
公开(公告)号：WO02083774A3
公开(公告)日：2003-04-10
申请号：PCT/US0211187
申请日：2002-04-10
申请人： UNIV RUTGERS , LI JING , HUANG XIAOYING
发明人： LI JING , HUANG XIAOYING
IPC分类号： C07F13/00 , H01L51/30 , H01L31/00
CPC分类号： H01L51/0032 , C07F13/005
摘要： Hybrid crystalline organic-inorganic quantum confined systems are disclosed, which contain alternating layers of a bifunctional organic ligand and a II-VI semiconducting chalcogenide, wherein the semiconducting chalcogenide layers contain chalcogenides have the formula MQ, in which M is independently selected from II-VI semiconductor cationic species and Q is independently selected from S, Se and Te; and the bifunctional organic ligands of each organic ligand layer are bonded by a first functional group to an element M of an adjacent II-VI semiconducting chalcogenide layer and by a second functional group to an element M from the adjacent opposing II-VI semiconducting chalcogenide layer, so that the adjacent opposing II-VI semiconducting chalcogenide layers are linked by the bifunctional organic ligands of the organic ligand layers. Optical absorption experiments show that these systems produce a significant blue shift in their optical absorption edges, 1.2-1.5 eV, compared to a shift of 1.0 electron volt by the best grown II-VI or III-V semiconducting quantum colloidal dots. In addition, the II-VI confined layers in these systems possess a perfectly periodic arrangement.
摘要翻译：公开了混合结晶有机 - 无机量子限制系统，其包含双官能有机配体和II-VI半导体硫族化物的交替层，其中半导体硫族化物层含有硫属化物，其具有式MQ，其中M独立地选自II-VI 半导体阳离子种类和Q独立地选自S，Se和Te; 并且每个有机配体层的双官能有机配体通过第一官能团与相邻的II-VI半导体硫族化物层的元素M和第二官能团键合到来自相邻的相反的II-VI半导体硫族化物层的元素M ，使得相邻的相对的II-VI半导体硫族化物层通过有机配体层的双功能有机配体连接。光学吸收实验表明，与通过最佳生长的II-VI或III-V半导体量子胶体点的1.0电子伏特的偏移相比，这些系统在其光吸收边缘产生显着的蓝移，为1.2-1.5eV。此外，这些系统中的II-VI限制层具有完美的周期性排列。

3. 发明申请

WO2004045759A3 POROUS POLYMERIC COORDINATION COMPOUNDS 审中-公开
标题翻译：多孔聚合物协同化合物
公开(公告)号：WO2004045759A3
公开(公告)日：2006-02-02
申请号：PCT/US0337269
申请日：2003-11-20
申请人： UNIV RUTGERS , LI JING , PAN LONG , HUANG XIAOYING
发明人： LI JING , PAN LONG , HUANG XIAOYING
IPC分类号： B01J20060101 , C07F15/00 , C07F15/06 , B01J23/75 , B01J31/04 , B01J31/06 , B01J31/18 , C08G79/00
CPC分类号： C07F15/065
摘要： The present invention describes three-dimensional porous coordination compounds, a method of making the compounds, and a method of using the compounds to contain reactants in a reaction, said compounds characterized by a plurality of sheets comprising a two-dimensional array of repeating structural units comprising at least one transition metal, one polyfunctional ligand and one exodentate ligand wherein: (1) at least one binding member of each said polyfunctional ligand is coordinated to transition metal atoms in two different repeating structural units within one sheet; (2) said binding sites of each exodentate bridging ligand are coordinated to transition metal atoms in a each of two adjacent sheets, and (3) the ligands of the three-dimensional polymeric compound define channels and pores of molecular size throughout the structure of the compound.
摘要翻译：本发明描述了三维多孔配位化合物，一种制备该化合物的方法，以及一种在反应中使用该化合物含有反应物的方法，所述化合物的特征在于包括重复结构单元的二维阵列包括至少一种过渡金属，一种多官能配体和一种外分子配体，其中：（1）每个所述多官能配体的至少一个结合成员与一片中两个不同重复结构单元中的过渡金属原子配位; （2）每个外部桥接配体的所述结合位点与两个相邻片段中的每一个中的过渡金属原子配位，并且（3）三维聚合物的配体在整个结构中定义分子大小的通道和孔复合。

4. 发明申请

WO2002083774A2 HYBRID NANOSTRUCTURED MATERIALS BASED ON II-VI SEMICONDUCTORS 审中-公开
标题翻译：基于II-VI半导体的混合纳米结构材料
公开(公告)号：WO2002083774A2
公开(公告)日：2002-10-24
申请号：PCT/US2002/011187
申请日：2002-04-10
申请人： RUTGERS, THE STATE UNIVERSITY OF NEW JERSEY , LI, Jing , HUANG, Xiaoying
发明人： LI, Jing , HUANG, Xiaoying
IPC分类号： C08K
CPC分类号： H01L51/0032 , C07F13/005
摘要： Hybrid crystalline organic-inorganic quantum confined systems are disclosed, which contain alternating layers of a bifunctional organic ligand and a II-VI semiconducting chalcogenide, wherein the semiconducting chalcogenide layers contain chalcogenides have the formula MQ, in which M is independently selected from II-VI semiconductor cationic species and Q is independently selected from S, Se and Te; and the bifunctional organic ligands of each organic ligand layer are bonded by a first functional group to an element M of an adjacent II-VI semiconducting chalcogenide layer and by a second functional group to an element M from the adjacent opposing II-VI semiconducting chalcogenide layer, so that the adjacent opposing II-VI semiconducting chalcogenide layers are linked by the bifunctional organic ligands of the organic ligand layers. Optical absorption experiments show that these systems produce a significant blue shift in their optical absorption edges, 1.2-1.5 eV, compared to a shift of 1.0 electron volt by the best grown II-VI or III-V semiconducting quantum colloidal dots. In addition, the II-VI confined layers in these systems possess a perfectly periodic arrangement.
摘要翻译：公开了混合结晶有机 - 无机量子限制系统，其包含双官能有机配体和II-VI半导体硫族化物的交替层，其中半导体硫族化物层含有硫属化物，其具有式MQ，其中M独立地选自II-VI 半导体阳离子种类和Q独立地选自S，Se和Te; 并且每个有机配体层的双官能有机配体通过第一官能团与相邻的II-VI半导体硫族化物层的元素M和第二官能团键合到来自相邻的相反的II-VI半导体硫族化物层的元素M ，使得相邻的相对的II-VI半导体硫族化物层通过有机配体层的双功能有机配体连接。光学吸收实验表明，与通过最佳生长的II-VI或III-V半导体量子胶体点的1.0电子伏特的偏移相比，这些系统在其光吸收边缘产生显着的蓝移，为1.2-1.5eV。此外，这些系统中的II-VI限制层具有完美的周期性排列。

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