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1. 发明申请

WO1997035227A2 ELECTROCHROMIC OR PHOTOELECTROCHROMIC DEVICE 审中-公开
标题翻译：电致变色光电器件
公开(公告)号：WO1997035227A2
公开(公告)日：1997-09-25
申请号：PCT/CH1997000104
申请日：1997-03-13
申请人： ECOLE POLYTECHNIQUE FEDERALE DE LAUSANNE , BONHOTE, Pierre , WALDER, Lorenz , GRÄTZEL, Michael
发明人： ECOLE POLYTECHNIQUE FEDERALE DE LAUSANNE
IPC分类号： G02F01/15
CPC分类号： B82Y20/00 , G02F1/15 , G02F1/155 , G02F2202/36
摘要： Electrochromic and photoelectrochromic devices using nanocrystalline semiconductor electrodes with a high specific surface area and surface-absorbed electrochromic molecules are disclosed.
摘要翻译：公开了使用具有高比表面积的纳米晶体半导体电极和表面吸收的电致变色分子的电致变色和光电致变色器件。

2. 发明申请

WO2006131873A2 LITHIUM RECHARGEABLE ELECTROCHEMICAL CELL 审中-公开
标题翻译：锂可充电电化学细胞
公开(公告)号：WO2006131873A2
公开(公告)日：2006-12-14
申请号：PCT/IB2006/051781
申请日：2006-06-02
申请人： HIGH POWER LITHIUM S.A. , GRÄTZEL, Michael , EXNAR, Ivan , WANG, Qing
发明人： GRÄTZEL, Michael , EXNAR, Ivan , WANG, Qing
IPC分类号： H01M4/62 , H01M4/02 , H01M4/04
CPC分类号： H01M4/131 , H01M4/0416 , H01M4/1391 , H01M4/624 , H01M10/0525 , H01M10/058
摘要： This invention concerns a lithium rechargeable electrochemical cell comprising an electrochemically addressable electrode system. The electrodes are composed of a cathodic lithium insertion material incorporating a p-type conductive compound, and an anodic lithium insertion material incorporating an n-type conductive compound. Such a rechargeable electrochemical cell is suitable for high energy density applications. The present invention also concerns the general use of conductive compounds and electrochemically addressable electrode systems comprising similar components which are suitable for use in the electrochemical cell.
摘要翻译：本发明涉及一种包含电化学可寻址电极系统的锂可再充电电化学电池。电极由掺有p型导电化合物的阴极锂插入材料和掺入n型导电化合物的阳极锂插入材料构成。这种可充电电化学电池适用于高能量密度应用。本发明还涉及导电化合物和电化学可寻址电极系统的一般用途，其包括适合用于电化学电池的类似组分。

3. 发明申请

WO1992014836A1 SENSOR FOR MEASURING THE QUANTITY OF A DISSOLVED COMPONENT 审中-公开
标题翻译：用于测量解散组件数量的传感器
公开(公告)号：WO1992014836A1
公开(公告)日：1992-09-03
申请号：PCT/CH1992000034
申请日：1992-02-19
申请人： ASULAB S.A. , GRÄTZEL, Michael , FRASER, David , ZAKEERUDDIN, Shaik, Mohammed , RANDIN, Jean-Paul , FRENKEL, Erik, Jan
发明人： ASULAB S.A.
IPC分类号： C12Q01/00
CPC分类号： C12Q1/006 , C12Q1/004 , Y10S435/817
摘要： The aim of the invention is to improve existing amperometric sensors used to measure the quantity of a component present in a solution. This aim is reached by using a sensor provided with a measuring electrode (20) having at least one current collector (37) electrically connected at one of the electric contacts (34) and coated with a mixture (38) comprising at least one oxido-reduction enzyme specific to said component and at least one mediator transfering the electrons between said enzyme et said current collector, characterized in that the mediator is selected amongst the complexes of a transition metal with at least one bipyridine, terpyridine or phenanthroline ligand substituted by at least one electron donor group. Said sensor is applicable more particularly to the detection of glucose.

4. 发明申请

WO2007116363A2 LITHIUM RECHARGEABLE ELECTROCHEMICAL CELL 审中-公开
标题翻译：锂可充电电化学细胞
公开(公告)号：WO2007116363A2
公开(公告)日：2007-10-18
申请号：PCT/IB2007/051246
申请日：2007-04-06
申请人： HIGH POWER LITHIUM S.A. , EXNAR, Ivan , WANG, Qing , GRÄTZEL, Michael , ZAKEERUDDIN, Shaik Mohammed , KAVAN, Ladislav
发明人： EXNAR, Ivan , WANG, Qing , GRÄTZEL, Michael , ZAKEERUDDIN, Shaik Mohammed , KAVAN, Ladislav
IPC分类号： H01M10/40 , H01M4/04
CPC分类号： H01M10/0525 , H01B1/122 , H01M4/13 , H01M4/5825 , H01M10/0562 , H01M10/0565 , H01M10/0567 , H01M10/058 , H01M2300/0025
摘要： This invention concerns a lithium rechargeable electrochemical cell containing electrochemical redox active compounds in the electrolyte. The cell is composed of two compartments, where the cathodic compartment comprises a cathodic lithium insertion material and one or more of p-type redox active compound(s) in the electrolyte; the anodic compartment comprises an anodic lithium insertion material and one or more of n-type redox active compound(s) in the electrolyte. These two compartments are separated by a separator and the redox active compounds are confined only in each compartment. Such a rechargeable electrochemical cell is suitable for high energy density applications. The present invention also concerns the general use of redox active compounds and electrochemically addressable electrode systems containing similar components which are suitable for use in the electrochemical cell.
摘要翻译：本发明涉及在电解质中含有电化学氧化还原活性化合物的锂可再充电电化学电池。电池由两个室组成，其中阴极室包括阴极锂插入材料和电解质中的一种或多种p型氧化还原活性化合物; 阳极室包含阳极锂插入材料和电解质中的一种或多种n型氧化还原活性化合物。这两个隔室由分离器分开，氧化还原活性化合物仅限于每个隔间。这种可充电电化学电池适用于高能量密度应用。本发明还涉及氧化还原活性化合物和包含适用于电化学电池的类似成分的电化学可寻址电极系统的一般用途。

5. 发明申请

WO1992014741A1 MONO, BIS OR TRIS (2,2'-SUBSTITUTED BIPYRIDINE) COMPLEXES OF A METAL SELECTED AMONGST IRON, RUTHENIUM, OSMIUM OR VANADIUM AND PREPARATION METHODS THEREOF 审中-公开
标题翻译： MONO，BIS或TRIS（2,2'-取代的苄嘧啶）选择的金属，铁，矾土或钒的金属络合物及其制备方法
公开(公告)号：WO1992014741A1
公开(公告)日：1992-09-03
申请号：PCT/CH1992000033
申请日：1992-02-19
申请人： ASULAB S.A. , GRÄTZEL, Michael , FRASER, David , NAZEERUDDIN, Mohammed, Khaja , ZAKEERUDDIN, Shaik, Mohammed
发明人： ASULAB S.A.
IPC分类号： C07F15/00
CPC分类号： C07F15/0026 , C07F9/005 , C07F15/0053 , C07F15/025 , C12Q1/004 , H01L51/0084 , H01L51/0086
摘要： The present invention relates to a new family of mono, bis or tris (2,2'-substituted bipyridine) complexes of a metal selected amongst iron, ruthenium, osmium or vanadium, the bipyridine being substituted by at least one electron donor group. According to the invention, said electron donor group is selected amongst a hydroxy group, an alkoxy group, an aryloxy group or a primary, secondary or tertiary amine group. The invention also relates to the method for the preparation of such complexes.

6. 发明授权

US06734305B2 Electrochromic or photoelectrochromic device 失效
标题翻译：电致变色或光电色装置
公开(公告)号：US06734305B2
公开(公告)日：2004-05-11
申请号：US10165318
申请日：2002-06-07
申请人： Bonhôte Pierre , Walder Lorenz , Grätzel Michael
发明人： Bonhôte Pierre , Walder Lorenz , Grätzel Michael
IPC分类号： C07D24146
CPC分类号： B82Y20/00 , G02F1/15 , G02F1/155 , G02F2202/36
摘要： An electrochromic or photoelectrochromic device possessing the property of changing color under the effect of an electric voltage and/or of a variation in the intensity of a light radiation, this device comprising at least one cathode and one anode, at least one of these electrodes being constituted at least in part of a transparent or translucent substrate bearing an electrically conductive coating, and an electrolyte arranged between these electrodes, and an electric circuit connecting said cathode and anode, characterized in that at least one of these electrodes carries a coating constituted of at least one nanocrystalline layer of at least one semiconductive material, having a roughness factor equal to at least 20, and a monolayer of electrically active molecules or of an electrically active polymer, said monolayer being absorbed on the surface of this coating, and in that the device contains at least one auxiliary electrically active compound, possibly dissolved in the electrolyte, having the property of being capable of being oxidized or reduced in a reversible manner.
摘要翻译：一种具有在电压和/或光辐射强度变化下变色的性质的电致变色或光电变色装置，该装置包括至少一个阴极和一个阳极，这些电极中的至少一个为构成至少部分具有导电涂层的透明或半透明基板和布置在这些电极之间的电解质，以及连接所述阴极和阳极的电路，其特征在于，这些电极中的至少一个承载由至少一个半导体材料的至少一个纳米晶层，具有等于至少20的粗糙度因子，以及单层电活性分子或电活性聚合物，所述单层被吸收在该涂层的表面上，装置含有至少一种可能溶解在电解质中的辅助电活性化合物具有能够以可逆方式氧化或还原的性质。

7. 发明申请

WO2008047324A3 NANOTUBE WIRING 审中-公开
公开(公告)号：WO2008047324A3
公开(公告)日：2008-04-24
申请号：PCT/IB2007/054246
申请日：2007-10-18
申请人： HIGH POWER LITHIUM S.A. , EXNAR, Ivan , ZAKEERUDDIN, Shaik Mohammed , GRÄTZEL, Michael , KAVAN, Ladislav
发明人： EXNAR, Ivan , ZAKEERUDDIN, Shaik Mohammed , GRÄTZEL, Michael , KAVAN, Ladislav
IPC分类号： H01M10/40 , H01M4/04 , H01M2/16 , H01M4/36
摘要： This invention concerns a novel method for surface derivatization of electrode materials for Li-ion batteries. The derivatization is based on adsorption of a composite assembly consisting of amphiphilic redox active molecule attached to single walled carbon nanotube (SWCNT). Its role consists in the enhancement of electronic conductivity of electrode materials, such as phosphate olivines, without requesting any significant increase of the electrode volume and mass. The SWCNT is linked to the redox molecule via non-covalent or covalent interaction with the hydrophobic part of the molecule or electrostatic interaction. The hydrophilic part of the molecule serves as the anchoring site for surface modification of the electrode active material. The redox potential of the molecule is close to the redox potential of the electrode active material. The adsorbed assembly of redox-molecule & SWCNT thus improves the charge transfer from a current collector to the electrode active material.

8. 发明申请

WO1998021764A1 RADIATION DETECTOR 审中-公开
标题翻译：辐射探测器
公开(公告)号：WO1998021764A1
公开(公告)日：1998-05-22
申请号：PCT/EP1997006050
申请日：1997-11-03
申请人： HOECHST RESEARCH & TECHNOLOGY DEUTSCHLAND GMBH & CO. KG , SALBECK, Josef , GRÄTZEL, Michael
发明人： HOECHST RESEARCH & TECHNOLOGY DEUTSCHLAND GMBH & CO. KG
IPC分类号： H01L51/30
CPC分类号： H01L51/0052 , G01J1/429 , H01L31/09 , H01L51/0059 , H01L51/0069 , H01L51/007 , H01L51/0071 , H01L51/0094 , H01L51/4226 , H01L2251/306
摘要： An optoelectric radiation detector detecting short wave electromagnetic radiation, characterized by a charge transfer layer containing a hole conduction material.
摘要翻译：用于检测短波电磁辐射的光电子辐射检测器的特征在于包括一个空穴导体材料的电荷输送层。

9. 发明申请

WO1997012382A1 PROCESS FOR MANUFACTURING AN ELECTRODE FOR AN ELECTROCHEMICAL DEVICE 审中-公开
标题翻译：用于制造电化学装置的电极的方法
公开(公告)号：WO1997012382A1
公开(公告)日：1997-04-03
申请号：PCT/IB1995000786
申请日：1995-09-25
申请人： ECOLE POLYTECHNIQUE FEDERALE DE LAUSANNE , PAPPAS, Nicholas , GRÄTZEL, Michael
发明人： ECOLE POLYTECHNIQUE FEDERALE DE LAUSANNE
IPC分类号： H01G09/20
CPC分类号： H01G9/2031 , Y02E10/542 , Y02P70/521
摘要： The present invention aims at improving the catalytic activity of the metallic platinum deposited on the substrate of the counterelectrode (i.e. the cathode), so as to obtain a high value of the catalytic activity on the reduction reaction of triiodide to iodide essentially independant of the nature of the solvent used in the electrolyte. To that effect, the manufacturing process according to the invention is characterized in that said metallic platinum is deposited in the form of a plurality of spheroidal microcrystallite clusters each having a size of less than about 100 nanometers, dispersed over the surface of said substrate, and in that said deposited metallic platinum is submitted to a thermal treatment, carried out at a temperature in the range of about 375 to 400 DEG C, so as to enhance the catalytic properties of the platinum on the oxido-reduction reaction of iodine and triiodide 3I2 + 2e 2I3 in the redox system iodine/iodide.
摘要翻译：本发明旨在提高沉积在对电极（即阴极）基底上的金属铂的催化活性，从而获得三碘化物与碘化物的还原反应对催化活性的高值，其基本上独立于自然界的电解质中使用的溶剂。为此，根据本发明的制造方法的特征在于，所述金属铂以多个球状微晶簇的形式沉积，每个微球簇具有小于约100纳米的尺寸，分散在所述衬底的表面上，以及因为所述沉积的金属铂进行热处理，在约375-400℃的温度下进行，以提高铂对碘和三碘化物3I2的氧化还原反应的催化性能 + 2e < - > <==> 2I3 < - >在氧化还原体系碘/碘化物中。

10. 发明申请

WO1995029924A1 PHOSPHONATED POLYPYRIDYL COMPOUNDS AND THEIR COMPLEXES 审中-公开
标题翻译：磷酸化聚吡咯化合物及其复合物
公开(公告)号：WO1995029924A1
公开(公告)日：1995-11-09
申请号：PCT/IB1994000088
申请日：1994-05-02
申请人： ECOLE POLYTECHNIQUE FEDERALE DE LAUSANNE (EPFL) , GRÄTZEL, Michael , KOHLE, Oliver , NAZEERUDDIN, Mohammad, K. , PECHY, Péter , ROTZINGER, François, P. , RUILE, Stephan , ZAKEERUDDIN, Shaik, Mohammad
发明人： ECOLE POLYTECHNIQUE FEDERALE DE LAUSANNE (EPFL)
IPC分类号： C07F09/58
CPC分类号： A61K51/0478 , A61K51/0489 , A61K2123/00 , C07F9/58 , C07F15/0053 , C09B57/10 , H01G9/2031 , H01G9/2059 , H01L51/0086
摘要： A compound, in metal-free or metal complex form of formula (1) to (3) in which R is hydrogen or C1-30 alkyl; X is hydrogen, halogen (preferably Cl or Br) or C1-30 alkyl.
摘要翻译：式（1）至（3）的金属或金属络合物形式的化合物，其中R是氢或C 1-3烷基; X是氢，卤素（优选Cl或Br）或C 1-3烷基。

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