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    • 1. 发明专利
    • Method for efficiently removing hazardous component in contaminated water
    • 有效去除污染水中危险成分的方法
    • JP2014131791A
    • 2014-07-17
    • JP2013045208
    • 2013-03-07
    • Fumio Maekawa文男 前川Masayo Maekawa雅代 前川
    • MAEKAWA FUMIOMAEKAWA MASAYO
    • C02F1/58C02F1/52G21F9/12
    • PROBLEM TO BE SOLVED: To provide a method and a device for purifying water for the purpose of providing safe purified water by removing hazardous components in contaminated water like a radioactive substance such as cesium, arsenic or the like.SOLUTION: In a method and a device for purifying water, a method for efficiently removing a hazardous ion component in contaminated water by adding any one or two metal cations selected from Ca, Mg, Fe, and Al and/or any one or two anions selected from a phosphate ion, a sulfate ion, a silicate ion, and a hydroxide ion thereto so that an ion component dissolved therein (dissolved state) is changed to colloid in form, and subsequently bringing the colloid into contact with a fine particulate ion exchange resin excellent in physical adsorption function with an average particle diameter of 30 μ or less is applied. The fine particulate ion exchange resin with lowered capacity is regenerated and reused in repetition by bringing the fine particulate ion exchange resin having fine particulate colloid adsorbed thereto into contact with one or two or more of an acid-containing aqueous solution and an alkali-containing aqueous solution, and desorbing the fine particulate colloid from the fine particulate ion exchange resin.
    • 要解决的问题:提供一种净化水的方法和装置,其目的是通过除去诸如铯,砷等放射性物质的污染水中的有害成分来提供安全的净化水。方法和方法 用于净化水的装置,通过添加选自Ca,Mg,Fe和Al中的一种或两种金属阳离子和/或选自磷酸根离子,任选的一种或两种阴离子来有效地除去污染水中的危险离子组分的方法 硫酸根离子,硅酸盐离子和氢氧根离子,使其中溶解的离子成分(溶解状态)变成胶体,随后使胶体与物理吸附功能优异的微粒离子交换树脂接触, 平均粒径为30μ以下。 通过使吸附有微粒状胶体的微粒离子交换树脂与一种或两种以上的含酸水溶液和含碱水溶液接触,可以再次再次使用具有低容量的细粒状离子交换树脂 溶液,并从细颗粒离子交换树脂中解吸细颗粒胶体。
    • 2. 发明专利
    • Method for purifying water using powder ion exchange resin inclusion adsorber as filtration layer
    • 使用粉末离子交换树脂包裹水作为过滤层的水净化方法
    • JP2012179001A
    • 2012-09-20
    • JP2011043534
    • 2011-03-01
    • Fumio Maekawa文男 前川
    • MAEKAWA FUMIO
    • A01K63/04A01G31/00C02F3/10C02F3/28
    • Y02W10/15
    • PROBLEM TO BE SOLVED: To provide a water purifying method that facilitates rearing of aquarium fish and hydroponic culture of plants by allowing a solution in a closed water region to flow through a bioreactor prepared by adsorbing a colloid containing a biofilm in water as a main component, by a powder ion exchange resin inclusion adsorber.SOLUTION: A filtration adsorber containing powder ion exchange resin, preferably anion powder ion exchange resin, further preferably anion-cation powder ion exchange resin is used as an organism filtration material for fish breeding water in the closed water region and a circulating culture solution in a plant factory, and an aqueous solution that suspends the colloid containing the biofilm as the main component, is brought into contact with the filtration adsorber. The powder ion exchange resin thereby adsorbs the colloid containing noxious components to not only generate transparent liquid but to reduce the blow frequency of water in use, thereby preparing the filtration absorber having an excellent organism filtrating function without causing the death of the aquarium fish and growth impediment of plants due to toxin component eluted from the biofilm which has been the greatest concern, even if the water is used as it is.
    • 要解决的问题:提供一种水净化方法,其通过使封闭水区域中的溶液流过通过将含有生物膜的胶体吸附在水中而制备的生物反应器来促进水族馆鱼类的培养和水培培养, 主要成分为粉末离子交换树脂夹杂物吸附剂。 解决方案:使用含有粉末离子交换树脂,优选阴离子粉末离子交换树脂的过滤吸附剂,进一步优选阴离子 - 阳离子粉末离子交换树脂作为封闭水域中的鱼类养殖水的生物过滤材料和循环培养物 与含有生物膜作为主要成分的胶体悬浮的水溶液与过滤吸附剂接触。 粉末离子交换树脂从而吸附含有有害成分的胶体,不仅产生透明液体,而且降低了使用中的水的吹风频率,从而制备了具有优异生物过滤功能的过滤吸收器,而不会导致水族箱鱼的死亡和生长 即使水被直接使用,由于毒素成分被从生物膜中洗脱出来的植物受到最大关注的阻碍。 版权所有(C)2012,JPO&INPIT
    • 3. 发明专利
    • Method for manufacturing particulate titanium oxide-containing powdery ion exchange resin adsorbent, and method and apparatus for cleaning air or water using the same
    • 含氧化钛氧化物粉末离子交换树脂吸附剂的制造方法以及使用其清洁空气或水的方法和装置
    • JP2004203988A
    • 2004-07-22
    • JP2002373423
    • 2002-12-25
    • Fumio MaekawaKoji Nukui文男 前川興治 貫井
    • MAEKAWA FUMIONUKUI KOJI
    • A61L9/00A61L9/01A61L9/16B01J20/26C02F1/30C02F1/42C02F1/72C08J3/205
    • PROBLEM TO BE SOLVED: To provide a technique for improving the environment of a residence space by removing pet odors, disinfectant odors, cooking odors or bad smells from a production site and air-cleaning, or for easily and inexpensively sanitizing water including waste water from a factory.
      SOLUTION: A powdery ion exchange resin-fiber adsorbent comprises a particulate titanium oxide-containing powdery ion exchange resin adsorbent for purifying air or water, and exhibits excellent functions for reacting with a floating dust or a bad smell component thereby adsorbing and removing them while titanium oxide for a photocatalyst exhibits an excellent bad smell-decomposing function. There are provided a manufacturing method and a utilizing method of a new material exhibiting enhanced synergetic effects by combining these two functions, and an apparatus therefor. The technique enables to utilize waste articles/recycled articles as a raw material of the new material and is simply and inexpensively applied in a wide range of applications.
      COPYRIGHT: (C)2004,JPO&NCIPI
    • 要解决的问题:提供一种通过从生产现场去除宠物气味,消毒臭味,烹饪气味或气味异味或空气清洁来改善居住空间的环境的技术,或者容易且廉价地消毒水,包括 工厂废水。 解决方案:粉末状离子交换树脂纤维吸附剂包括用于净化空气或水的颗粒状氧化钛粉末状离子交换树脂吸附剂,并且具有优异的与浮尘或不良气味组分反应的功能,从而吸附和去除 它们同时用作光催化剂的氧化钛表现出极好的不良气味分解功能。 提供了通过组合这两个功能而具有增强的协同效应的新材料的制造方法和利用方法及其装置。 该技术可以利用废物/再生制品作为新材料的原料,并且在广泛的应用中简单且低成本地应用。 版权所有(C)2004,JPO&NCIPI
    • 4. 发明专利
    • Method of refining water-containing oil and apparatus therefor
    • 精炼含水油的方法及其设备
    • JP2013141633A
    • 2013-07-22
    • JP2012002664
    • 2012-01-11
    • Fumio Maekawa文男 前川
    • MAEKAWA FUMIONUKUI KOJITOFUN HITOSHI
    • B01D15/04B01J20/26B01J20/34B01J39/04B01J49/00C10L1/32
    • PROBLEM TO BE SOLVED: To provide a method of refining water and/or oil being a raw material, in a method for producing compatible transparent water-containing oil stably keeping a homogeneous state without causing milkiness while oil and water are mixed, and furthermore, a method of refining coarse water-containing oil emulsion containing a turbid component, and an apparatus therefor.SOLUTION: There are provided a series of refining method of water-containing oil and an apparatus therefor in a production system of obtaining emulsion by blending at least one kind of oil supplied from mineral oil and vegetable oil, water and an emulsifier. The refining method includes: (1) a process of bringing the water and/or material oil becoming the raw material into contact reaction with an adsorbent comprising a powder ion exchange resin, preferably a powder ion exchange resin-containing porous support body; (2) a process of refining the water-containing oil, in which the coarse water-containing oil emulsion containing the turbid component produced in the production process is brought into contact reaction with the adsorbent comprising the powder ion exchange resin, preferably the powder ion exchange resin-containing porous support body; and (3) a process of regenerating the powder ion exchange resin used in the refining process and lowered in the cleaning capacity by using a polar organic solvent, preferably acetone.
    • 要解决的问题:提供一种精炼作为原料的水和/或油的方法,在混合油和水的同时,在兼容的透明含水油的制造方法中,在均匀状态下不引起挤奶,同时, 一种精炼含有浑浊成分的粗含水油乳液的方法及其装置。其中,提供了一系列含水油的精制方法及其制备方法,该制备方法至少通过混合得到乳液 一种从矿物油和植物油,水和乳化剂中提供的油。 精炼方法包括:(1)使水和/或原料油成为原料的方法与包含粉末离子交换树脂,优选含粉末离子交换树脂的多孔支撑体的吸附剂接触反应; (2)一种精制含水油的方法,其中含有在生产过程中生产的浑浊成分的粗含水油乳液与包含粉末离子交换树脂的吸附剂接触反应,优选粉末离子 交换含树脂的多孔支撑体; 和(3)在精炼过程中使用的粉末离子交换树脂再生过程,并使用极性有机溶剂,优选丙酮降低清洗能力。
    • 5. 发明专利
    • Liquid composition mainly composed of powder ion exchange resin, and powder ion exchange resin-including support
    • 主要由粉末离子交换树脂和粉末离子交换树脂组成的液体组合物,包括支持
    • JP2012011348A
    • 2012-01-19
    • JP2010151942
    • 2010-07-02
    • Fumio Maekawa文男 前川
    • MAEKAWA FUMIO
    • B01J47/12A01G1/00A61L9/01B01J39/04B01J41/04B01J49/00C02F1/42C13B20/14
    • PROBLEM TO BE SOLVED: To provide a technique for preparing a homogeneous liquid composition mainly composed of a powder ion exchange resin, and a method for use thereof.SOLUTION: A liquid composition having an optional adhesive force is prepared by performing mixing and stirring treatment in a solution while adjusting the mixing ratio of a fine fibrous compound to the powder ion exchange resin, and this liquid composition is used to prepare a powder ion exchange resin-including processed product in which the powder ion exchange resin is adhered to a support. The liquid composition with a mixing ratio of the fine fibrous compound to the powder ion exchange resin of 5-100 wt.% is mixed and applied to the support followed by dehydration and drying, whereby an element for filtration machine or a deodorant sheet in which the powder ion exchange resin is inseparably fixed to a surface layer can be produced. By reducing the mixing ratio of the fine fibrous compound to 10 wt.% or less, a homogenous liquid composition mainly composed of the powder ion exchanged resin with reduced adhesive force to the support is prepared, and this liquid composition is used, whereby a hand spray enhanced in operability while preventing clogging of a spray nozzle can be produced.
    • 要解决的问题:提供一种主要由粉末离子交换树脂组成的均匀液体组合物的制备技术及其使用方法。 解决方案:通过在调节细纤维化合物与粉末离子交换树脂的混合比例的溶液中进行混合搅拌处理来制备具有任选粘附力的液体组合物,并且使用该液体组合物来制备 粉末离子交换树脂 - 其中粉末离子交换树脂粘附到载体上的加工产品。 将具有5-100重量%的细纤维化合物与粉末离子交换树脂的混合比的液体组合物混合并施加到载体上,然后进行脱水和干燥,由此将用于过滤机或除臭剂片的元件 粉末离子交换树脂不可分割地固定在表层可以生产。 通过将细纤维化合物的混合比例降低到10重量%以下,制备主要由粉末离子交换树脂组成的均匀液体组合物,其对载体具有降低的粘合力,并且使用该液体组合物,由此使用一种手 可以产生喷雾,同时防止喷嘴堵塞。 版权所有(C)2012,JPO&INPIT
    • 6. 发明专利
    • Deodorant using used ion exchange resin and method for producing the same
    • 使用离子交换树脂的脱模剂及其制造方法
    • JP2005102674A
    • 2005-04-21
    • JP2003376311
    • 2003-09-30
    • Fumio Maekawa文男 前川
    • MAEKAWA FUMIOMAEKAWA MASAYO
    • A01K1/035A01K1/015B01J20/26B09B3/00
    • PROBLEM TO BE SOLVED: To effectively reuse used ion exchange resins by recycling, especially for chemically deodorize bad odor components by crushing cation exchanging resins into powder, remarkably increasing adsorption performance and bringing the pulverized ion exchange resins to contact with bad odors of ingredients represented by organic acids, ammonia, amines presenting in excretion of animals.
      SOLUTION: Deodorization function of powdery ion exchange resins is applied to cat sand, and an auxiliary filler to cat sand is provided by using the powdery ion exchange resins easily handled and easily expressing deodorization function. Preferably, a method for producing porous granules having 0.1-10 mm size by recyclingly using used granular ion exchange resins is provided. A new field for effectively using the ion exchange resins which are industrial wastes and a method for cleaning the environment by powdery ion exchange resins including cation exchange resins which have been hardly used are provided.
      COPYRIGHT: (C)2005,JPO&NCIPI
    • 要解决的问题:为了有效利用再利用的离子交换树脂,特别是通过将阳离子交换树脂粉碎成粉末来对臭气成分进行化学除臭,显着提高吸附性能,并使粉碎的离子交换树脂与不良气味接触 由有机酸代表的成分,氨,排泄动物的胺。 解决方案:将粉末状离子交换树脂的除臭功能应用于猫砂,并通过使用容易处理的粉末状离子交换树脂并容易地表现除臭功能来提供猫砂辅助填料。 优选地,提供了通过循环使用使用的粒状离子交换树脂来制造具有0.1-10mm尺寸的多孔颗粒的方法。 提供了一种有效利用作为工业废弃物的离子交换树脂的新领域,并且提供了几乎不使用的包括阳离子交换树脂的粉末状离子交换树脂来清洁环境的方法。 版权所有(C)2005,JPO&NCIPI
    • 8. 发明专利
    • Simple planter
    • 简单的飞机
    • JP2003052248A
    • 2003-02-25
    • JP2001277268
    • 2001-08-09
    • Fumio Maekawa文男 前川
    • MAEKAWA FUMIOMAEKAWA MASAYO
    • A01G27/00A01G9/02A01G27/04A47G7/02
    • PROBLEM TO BE SOLVED: To provide a simple planter that can clean the water for breeding ornamental fishes and feed water to plants. SOLUTION: A planter system is equipped with filtration layers 3, 8 mainly made of ion-exchange resins between a water tank 6 and the planter 2 and water in the tank 6 flows through the roots of the plants. Ion-exchange resins, particularly fine particles of ion exchange resin are used not only to retain the clarity of the water but also promote the activity of nitrobactria and denitrifying bacteria whereby the accumulation of contaminants, particularly nitrogen compounds is reduced in the water so that the plant can be grown. Owing to the growth, air is kept clean, is filled with aromas and nitrogen components in water are reduced. This invention facilitates the cultivation of horticulture plants, and both of aquarium and horticulture can be enjoyed when necessary. Particularly, this planter system can be used for aged people that have bedridden to give them rich and cure emotions. Since used ion exchange resins are utilized in this system, the system has a large significance for recycle of resources.
    • 要解决的问题:提供一种简单的播种机,可以清洗用于养殖观赏鱼和给植物的水的水。 解决方案:播种机系统在水箱6和播种机2之间装有主要由离子交换树脂制成的过滤层3,8,罐6中的水流过植物根部。 使用离子交换树脂,特别是离子交换树脂的细颗粒不仅用于保持水的透明度,而且还促进硝酸盐和反硝化细菌的活性,由此污染物,特别是氮化合物的积聚在水中降低, 植物可以种植。 由于生长,空气保持清洁,充满香气,氮气成分在水中减少。 本发明有利于栽培园艺植物,必要时可以享用水族箱和园艺。 特别是,这种种植体系可以用于卧床不起的老年人,给他们丰富和治愈情绪。 由于在该系统中使用了离子交换树脂,因此该系统对资源的循环利用具有重要意义。
    • 10. 发明授权
    • Method for refining sugar liquor
    • 糖液精制方法
    • US4968353A
    • 1990-11-06
    • US381115
    • 1989-07-14
    • Kohji KawasakiFumio Maekawa
    • Kohji KawasakiFumio Maekawa
    • C13B20/12C13B20/14
    • C13B20/123C13B20/14
    • A method for refining a sugar liquor by cristobalite and an ion exchange resin, and a method for refining the sugar liquor by a novel ion exchange resin refining system, are disclosed. Cristobalite exhibits specific adsorbant properties for various colloidal or suspended substances, while the ion exchange resin exhibits superior decoloring and desalting properties with respect to colorants and salts. By combining refining by cristobalite and refining by the ion exchange resin, there is provided a sugar refining system whereby even non-washed sugar liquor may be refined. The ion exchange resin refining system of the present invention includes three series of adsorption towers. Each series basically consists of a strongly basic anion exchange resin and a weakly acidic cation exchange resin, and the towers of each of these three series are shifted in a sequence of the pre-stage adsorption tower, the adsorption tower for regeneration, the post-stage adsorption tower and again back to the pre-stage adsorption tower, so that the ability of the strongly basic anion exchange resin may be displayed to the utmost, while the colorant adsorbant properties and the deanionation properties may be exhibited effectively.
    • 公开了通过方英石和离子交换树脂精制糖液的方法,以及通过新颖的离子交换树脂精制系统对糖液进行精制的方法。 方石英表现出对各种胶体或悬浮物质的特殊吸附性能,而离子交换树脂对于着色剂和盐表现出优异的脱色和脱盐性能。 通过将方英石精炼与离子交换树脂精炼相结合,提供了一种糖精炼系统,即使未洗涤的糖液也可以被精制。 本发明的离子交换树脂精制系统包括三个吸附塔系列。 每个系列基本上由强碱性阴离子交换树脂和弱酸性阳离子交换树脂组成,这三个系列中的每一个的塔都按前期的吸附塔,再生的吸附塔, 并且再次回到前级吸附塔,从而可以最大限度地显示强碱性阴离子交换树脂的能力,同时可以有效地显示着色剂吸附剂性质和脱色性能。