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1. 发明申请

WO2012115746A8 KEROGENE RECOVERY AND IN SITU OR EX SITU CRACKING PROCESS 审中-公开
标题翻译： KEROGENE恢复和现场或EX SITU破碎过程
公开(公告)号：WO2012115746A8
公开(公告)日：2013-05-02
申请号：PCT/US2012022918
申请日：2012-01-27
申请人： EXXONMOBIL CHEM PATENTS INC , DAVIS S MARK , WOLFENBARGER JULIAN A , MEURER WILLIAM P , STELL RICHARD C
发明人： DAVIS S MARK , WOLFENBARGER JULIAN A , MEURER WILLIAM P , STELL RICHARD C
IPC分类号： C10G45/46 , B01J29/00 , B01J29/06 , C10G45/00
CPC分类号： E21B43/243 , C10G1/002 , C10G1/04 , C10G2300/1033 , C10G2300/107 , C10G2300/4006 , C10G2300/4037 , C10G2400/20 , C10G2400/30
摘要： A method of obtaining a thermal cracking feedstock for the production of olefins from an in-situ extracted oil-shale formation. The method comprises the steps of obtaining compositional analyses data for a set of in-situ extracted shale oils, the set of in-situ extracted shale oils produced at varied production temperatures and/or levels of lithostatic stress; determining from the compositional analyses data a value of a production temperature or a lithostatic stress that when achieved produces an in-situ extracted shale oil having a concentration of aromatics at or below a target level, the target level suitable for the production of olefins by thermal cracking; adjusting oil-shale formation extraction conditions to achieve the values for production temperature and/or lithostatic stress; and producing an in-situ extracted shale oil suitable for use as a thermal cracking feedstock for the production of olefins. A method for processing a hydrocarbon produced from a feed oil-shale formation to produce olefins is also provided.
摘要翻译：从原位提取的油页岩地层获得用于生产烯烃的热裂解原料的方法。该方法包括以下步骤：获得一组原位提取的页岩油的组成分析数据，该组在不同的生产温度和/或岩石静应力水平下产生的原位提取的页岩油; 从组成分析数据确定生产温度或岩石静力应力的值，当获得时产生具有等于或低于目标水平的芳烃浓度的原位提取的页岩油，适用于通过热量生产烯烃的目标水平开裂; 调整油页岩形成提取条件以达到生产温度和/或岩石静应力的值; 并生产适合用作生产烯烃的热裂解原料的原位萃取页岩油。还提供了一种用于处理由进料油页岩层产生的烃以产生烯烃的方法。

2. 发明申请

WO2013033580A3 HYDROPROCESSED PRODUCT 审中-公开
标题翻译：氢化产品
公开(公告)号：WO2013033580A3
公开(公告)日：2013-04-25
申请号：PCT/US2012053417
申请日：2012-08-31
申请人： EXXONMOBIL CHEM PATENTS INC , XU TENG , EDWARDS PAUL M , BROWN STEPHEN H , WANG FRANK C , DAVIS S MARK
发明人： XU TENG , EDWARDS PAUL M , BROWN STEPHEN H , WANG FRANK C , DAVIS S MARK
IPC分类号： C10G69/06 , C10G49/18
CPC分类号： C10G69/06 , C10G49/18 , C10G2300/301 , C10G2300/302 , C10G2400/30
摘要： The invention relates to a hydroprocessed product, such as a hydroprocessed steam cracker tar, that can be produced by hydroprocessing tar, such as a tar obtained from hydrocarbon pyrolysis. The in¬ vention also relates to methods for producing such a hydroprocessed product, and the use of such a product, e.g., as a fuel oil blending component.
摘要翻译：本发明涉及一种加氢处理产品，例如加氢蒸馏裂解焦油，其可通过加氢处理焦油（例如由烃热解获得的焦油）产生。本发明还涉及生产这种加氢处理产品的方法，以及这种产品如燃料油共混组分的使用。

3. 发明申请

WO2013033580A2 HYDROPROCESSED PRODUCT 审中-公开
标题翻译：氢化产品
公开(公告)号：WO2013033580A2
公开(公告)日：2013-03-07
申请号：PCT/US2012/053417
申请日：2012-08-31
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , XU, Teng , EDWARDS, Paul, M. , BROWN, Stephen, H. , WANG, Frank, C. , DAVIS, S., Mark
发明人： XU, Teng , EDWARDS, Paul, M. , BROWN, Stephen, H. , WANG, Frank, C. , DAVIS, S., Mark
CPC分类号： C10G69/06 , C10G49/18 , C10G2300/301 , C10G2300/302 , C10G2400/30
摘要： The invention relates to a hydroprocessed product that can be produced by hydroprocessing tar, such as a tar obtained from hydrocarbon pyrolysis. The invention also relates to methods for producing such a hydroprocessed product, and the use of such a product, e.g., as a fuel oil blending component.
摘要翻译：本发明涉及一种加氢处理产物，其可通过加氢处理焦油（例如由烃热解得到的焦油）来生产。本发明还涉及生产这种加氢处理产品的方法，以及这种产品的使用，例如作为燃料油混合组分。

4. 发明申请

WO2012005861A1 INTEGRATED PROCESS FOR STEAM CRACKING 审中-公开
标题翻译：蒸汽破碎综合工艺
公开(公告)号：WO2012005861A1
公开(公告)日：2012-01-12
申请号：PCT/US2011/039776
申请日：2011-06-09
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , DAVIS, S., Mark , STELL, Richard, C. , LIOU, Jiunn-shyan , BROWN, Stephen, H. , KEUSENKOTHEN, Paul, F. , DI NICOLANTONIO, Arthur, R. , WALDROP, Jason, J.
发明人： DAVIS, S., Mark , STELL, Richard, C. , LIOU, Jiunn-shyan , BROWN, Stephen, H. , KEUSENKOTHEN, Paul, F. , DI NICOLANTONIO, Arthur, R. , WALDROP, Jason, J.
IPC分类号： C10G9/00 , C10G9/32 , C10G55/04 , C10G9/36 , C07C4/04 , C07C47/00 , C10G51/02 , C10G9/06
CPC分类号： C10G9/005 , C10B55/00 , C10B55/10 , C10G9/007 , C10G9/36 , C10G51/023 , C10G2300/1077 , C10G2300/301 , C10G2300/4006 , C10G2300/708 , C10G2300/807 , C10G2400/20 , C10G2400/30
摘要： This invention relates to a process and system for cracking hydrocarbon feedstock containing vacuum resid comprising: (a) subjecting a vacuum resid to a first thermal conversion in a thermal conversion reactor (such as delayed coker, fluid coker, Flexicoker TM , visbreaker and catalytic hydro visbreaker) where at least 30 wt% of the vacuum resid is converted to material boiling below 1050°F (566°C); (b) introducing said thermally converted resid to a vapor/liquid separator, said separator being integrated into a steam cracking furnace, to form a vapor phase and liquid phase; (c) passing said vapor phase to the radiant furnace in said steam cracking furnace; and (d) recovering at least 30 wt% olefins from the material exiting the radiant furnace (based upon the weight of the total hydrocarbon material exiting the radiant furnace).
摘要翻译：本发明涉及一种用于裂化含有真空渣油的烃原料的方法和系统，该方法和系统包括：（a）在热转化反应器（例如延迟焦化器，流体焦化器，Flexicoker TM，减粘裂化器和催化氢化抗坏剂）中对真空渣油进行第一热转化），其中至少30重量％的真空渣油转化成沸点低于1050°F（566℃）的材料; （b）将所述热转化残渣引入蒸汽/液体分离器，所述分离器整合成蒸汽裂解炉，形成气相和液相; （c）将所述气相通过所述蒸汽裂解炉中的辐射炉; 和（d）从离开辐射炉的材料（基于离开辐射炉的总烃材料的重量）回收至少30重量％的烯烃。

5. 发明申请

WO2013033577A1 UPGRADING HYDROCARBON PYROLYSIS PRODUCTS 审中-公开
标题翻译：升级氢氟碳化物产品
公开(公告)号：WO2013033577A1
公开(公告)日：2013-03-07
申请号：PCT/US2012/053413
申请日：2012-08-31
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , BROWN, Stephen, H. , DAVIS, S., Mark , XU, Teng , REED, Keith, G. , BHASKER, Ananthakrishnan
发明人： BROWN, Stephen, H. , DAVIS, S., Mark , XU, Teng , REED, Keith, G. , BHASKER, Ananthakrishnan
IPC分类号： C10G69/06 , C10G49/18
CPC分类号： C10G69/06 , C10G49/18
摘要： The invention relates to upgraded pyrolysis products, processes for upgrading products obtained from hydrocarbon pyrolysis, equipment useful for such processes, and the use of upgraded pyrolysis products. A tar-containing stream recovered from the pyrolysis effluent is mixed with a utility fluid and subsequently hydroprocessed.
摘要翻译：本发明涉及升级的热解产物，用于升级由烃热解获得的产物的方法，用于这些方法的设备和使用升级的热解产物。将从热解流出物回收的含焦油流与实用流体混合，随后进行加氢处理。

6. 发明申请

WO2012115746A1 KEROGENE RECOVERY AND IN SITU OR EX SITU CRACKING PROCESS 审中-公开
标题翻译： KEROGENE恢复和现场或EX SITU破碎过程
公开(公告)号：WO2012115746A1
公开(公告)日：2012-08-30
申请号：PCT/US2012/022918
申请日：2012-01-27
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , DAVIS, S., Mark , WOLFENBARGER, Julian, A. , MEURER, William, P. , STELL, Richard, C.
发明人： DAVIS, S., Mark , WOLFENBARGER, Julian, A. , MEURER, William, P. , STELL, Richard, C.
IPC分类号： C10G45/46 , B01J29/06 , C10G45/00 , B01J29/00
CPC分类号： E21B43/243 , C10G1/002 , C10G1/04 , C10G2300/1033 , C10G2300/107 , C10G2300/4006 , C10G2300/4037 , C10G2400/20 , C10G2400/30
摘要： A method of obtaining a thermal cracking feedstock for the production of olefins from an in-situ extracted oil-shale formation. The method comprises the steps of obtaining compositional analyses data for a set of in-situ extracted shale oils, the set of in-situ extracted shale oils produced at varied production temperatures and/or levels of lithostatic stress; determining from the compositional analyses data a value of a production temperature or a lithostatic stress that when achieved produces an in-situ extracted shale oil having a concentration of aromatics at or below a target level, the target level suitable for the production of olefins by thermal cracking; adjusting oil-shale formation extraction conditions to achieve the values for production temperature and/or lithostatic stress; and producing an in-situ extracted shale oil suitable for use as a thermal cracking feedstock for the production of olefins. A method for processing a hydrocarbon produced from a feed oil-shale formation to produce olefins is also provided.
摘要翻译：从原位提取的油页岩地层获得用于生产烯烃的热裂解原料的方法。该方法包括以下步骤：获得一组原位提取的页岩油的组成分析数据，该组在不同的生产温度和/或岩石静应力水平下产生的原位提取的页岩油; 从组成分析数据确定生产温度或岩石静力应力的值，当获得时产生具有等于或低于目标水平的芳烃浓度的原位提取的页岩油，适用于通过热量生产烯烃的目标水平开裂; 调整油页岩形成提取条件以达到生产温度和/或岩石静应力的值; 并生产适合用作生产烯烃的热裂解原料的原位萃取页岩油。还提供了一种用于处理由进料油页岩层产生的烃以产生烯烃的方法。

7. 发明申请

WO2011090532A1 INTEGRATED PROCESS AND SYSTEM FOR STEAM CRACKING AND CATALYTIC HYDROVISBREAKING WITH CATALYST RECYCLE 审中-公开
标题翻译：用催化剂回收的蒸汽破碎和催化水解的综合方法和系统
公开(公告)号：WO2011090532A1
公开(公告)日：2011-07-28
申请号：PCT/US2010/055414
申请日：2010-11-04
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , DAVIS, S., Mark , KEUSENKOTHEN, Paul, F. , MCCONNACHIE, Jonathan, Martin , IACCINO, Larry, L. , STELL, Richard, C.
发明人： DAVIS, S., Mark , KEUSENKOTHEN, Paul, F. , MCCONNACHIE, Jonathan, Martin , IACCINO, Larry, L. , STELL, Richard, C.
IPC分类号： C10G9/36 , C10G47/02 , C10G69/06
CPC分类号： C10G9/36 , C10G47/06 , C10G69/06
摘要： This invention relates to a process for cracking hydrocarbon feedstock containing resid comprising: (a) heating a hydrocarbon feedstock containing resid; (b) adding molecular hydrogen to said heated feedstock to form a mixture stream; (c) adding a catalyst containing metal-sulfide particles to said heated feedstock and/or said mixture stream; (d) reacting said mixture in a catalytic hydrovisbreaking reactor under conditions of temperature, pressure and residence time sufficient to catalytically hydrovisbreak at least a portion of said resid into hydrovisbroken hydrocarbon components; (e) passing said reacted mixture stream into a high pressure separator and separating hydrogen from said reacted mixture; (f) passing said reacted mixture through a knockout drum to remove catalyst and unreacted or uncracked resid as a bottoms stream; and (g) passing said catalytically hydrovisbroken hydrocarbon components into a steam cracking furnace and thermally cracking said hydrocarbon components to form light olefins, alternately the knockout drum of step (f) is integrated into the steam cracking furnace of step (g).
摘要翻译：本发明涉及一种用于裂化含有残渣的烃原料的方法，该方法包括：（a）加热含有渣油的烃原料; （b）向所述加热的原料中加入分子氢以形成混合物流; （c）向所述加热的原料和/或所述混合物流中加入含有金属硫化物颗粒的催化剂; （d）使所述混合物在催化加氢脱硫反应器中在温度，压力和停留时间的条件下反应，足以将至少一部分所述残留物催化裂解成断裂的烃组分; （e）将所述反应的混合物流送入高压分离器并从所述反应的混合物中分离氢; （f）使所述反应的混合物通过脱料鼓以除去作为底部料流的催化剂和未反应的或未裂化的渣油; 和（g）将所述催化氢裂解烃组分通入蒸汽裂解炉中并热裂化所述烃组分以形成轻质烯烃，或者将步骤（f）的脱模鼓整合到步骤（g）的蒸汽裂解炉中。

8. 发明申请

WO2012005862A1 INTEGRATED VACUUM RESID TO CHEMICALS COVERSION PROCESS 审中-公开
标题翻译：一体化真空储存在化学品覆盖过程中
公开(公告)号：WO2012005862A1
公开(公告)日：2012-01-12
申请号：PCT/US2011/039782
申请日：2011-06-09
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , DAVIS, S., Mark , IACCINO, Larry, L. , STELL, Richard, C. , SILVERBERG, Steven, E. , LIOU, Jiunn-shyan , FREUND, Howard
发明人： DAVIS, S., Mark , IACCINO, Larry, L. , STELL, Richard, C. , SILVERBERG, Steven, E. , LIOU, Jiunn-shyan , FREUND, Howard
IPC分类号： C10G9/00 , C10G9/36 , C10G11/18 , C10G51/04 , C10J3/48
CPC分类号： C10G9/005 , C10G9/36 , C10G11/18 , C10G51/023 , C10G51/04 , C10G2300/4006 , C10G2300/4081 , C10G2300/708 , C10G2300/807 , C10G2400/20
摘要： A process and apparatus for cracking a hydrocarbon feed containing resid, comprising: heating a hydrocarbon feedstock containing resid; passing said heated hydrocarbon feedstock to a vapor/liquid separator; flashing said heated hydrocarbon feedstock in said vapor/liquid separator to form a vapor phase and a liquid phase containing said resid; passing at least a portion of said resid-containing liquid phase from said vapor/liquid separator to a thermal conversion reactor operating at 649°C or more, wherein the thermal conversion reactor contains coke particles; and converting at least a portion of said resid into olefins.
摘要翻译：一种用于裂化含有渣油的烃进料的方法和装置，包括：加热含有残渣的烃原料; 将所述加热的烃原料通入气/液分离器; 在所述气/液分离器中闪蒸所述加热的烃原料以形成含有所述残渣的气相和液相; 将来自所述蒸汽/液体分离器的至少一部分所述残留液体相转移到在649℃或更高温度下操作的热转化反应器，其中所述热转化反应器含有焦炭颗粒; 以及将所述残留物的至少一部分转化为烯烃。

9. 发明授权

US4959337A Wax isomerization catalyst and method for its production 失效
标题翻译：蜡异构化催化剂及其生产方法
公开(公告)号：US4959337A
公开(公告)日：1990-09-25
申请号：US283709
申请日：1988-12-13
申请人： Ian A. Cody , Hamner, deceased Glen P. , Willard H. Sawyer , Willard H. Sawyer , Davis S. Mark
发明人： Ian A. Cody , Hamner, deceased Glen P. , Willard H. Sawyer , Willard H. Sawyer , Davis S. Mark
IPC分类号： B01J23/40 , C10G45/62
CPC分类号： C10G45/62 , B01J23/40
摘要： A wax isomerization catalyst is described which comprises a Group VIII hydrogenation metal component on fluorided alumina or material containing alumina which catalyst possesses a surface nitrogen content N/Al ratio of about 0.01 or less determined by X-ray photoelectron spectroscopy, a bulk fluorine content of between about 2 to 10 wt %, a surface fluorine content defined as the amount of fluorine in a layer extending from the outer surface to a depth of about 1/100 of an inch of less than about 3 wt % provided that the surface fluoride concentration is less than the bulk fluoride concentration and an aluminum fluoride hydroxide hydrate peak height of 60 or less determined as the relative amount of hydrate represented by a peak in the X-ray diffraction pattern at 2.theta.=5.66 .ANG. when a hydrate level of 100 corresponds to the XRD peak height exhibited by a standard material. Also described is a method for producing a slack wax isomerization catalyst said method comprising depositing a Group VIII hydrogenation metal on alumina or material containing alumina extrudate, calcining said metal loaded extrudate, fluoriding said material using an aqueous fluorine source solution having a pH of 3.5 to 4.5 to a bulk fluorine level of about 8 wt % or less followed by heating in an air oxygen containing atmosphere or inert gas from ambient to 350.degree. to 450.degree. C. within 3 hours and holding at the final temperature, if necessary, for a time sufficient to reduce the hydrate and nitrogen contents to the aforesaid levels. Alternatively the catalyst can be made using a fluorine solution of pH less than 3.5 to a bulk fluorine level of about 10 wt % or less followed by heating in air or an oxygen containing atmosphere, or inert atmosphere at about 350.degree. to 450.degree. C.
摘要翻译：描述了一种蜡异构化催化剂，其包括在氟化氧化铝上的VIII族加氢金属组分或含有氧化铝的材料，该催化剂具有通过X射线光电子能谱测定的表面氮含量N / Al比为约0.01以下，体积氟含量在约2至10重量％之间，表面氟含量定义为从外表面延伸至约1/100英寸的深度小于约3重量％的层中的氟的量，条件是表面氟化物浓度小于氟化物浓度，氟化氢氢氧化物水合物峰值高度为60或更小，当水合物水平为100时，在2θ= 5.66时X射线衍射图中由峰值表示的水合物的相对量确定为对应于到标准材料表现出的XRD峰高。还描述了一种制备松散蜡异构化催化剂的方法，所述方法包括在氧化铝上沉积VIII族氢化金属或含有氧化铝挤出物的材料，煅烧所述负载有金属的挤出物，使用pH为3.5的含氟氟源溶液氟化所述材料， 4.5至大约8重量％或更少的体积氟水平，然后在3小时内在空气含氧气氛或惰性气体中从室温加热至350℃至450℃，并在必要时保持在最终温度时间足以将水合物和氮含量降低到上述水平。或者，催化剂可以使用pH小于3.5的氟溶液至约10重量％或更少的体积氟水平制备，然后在空气或含氧气氛中或在约350-450℃的惰性气氛下加热。

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