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1. 发明授权

US5403452A Method for determining gas concentrations and gas sensor with a solid electrolyte 失效
标题翻译：用固体电解质测定气体浓度和气体传感器的方法
公开(公告)号：US5403452A
公开(公告)日：1995-04-04
申请号：US930552
申请日：1992-09-28
申请人： Bernd Hielscher , Berthold Horn , Martin Schmah
发明人： Bernd Hielscher , Berthold Horn , Martin Schmah
IPC分类号： G01N27/416 , G01N27/48 , G01N27/49 , G01N27/26
CPC分类号： G01N27/4045
摘要： The invention relates to a method for determining the concentration of gases in a mixture of gasses by means of a gas sensor composed of three electrodes 1,2,3 and a solid electrolyte 4 upon the surface of which are secured the electrodes. A voltage Us being composed of a dc component Udc and an ac component Uac is applied to at least two electrodes, the measuring electrode 1 and the counter electrode 2. Us is controlled with reference to the reference electrode 3. The voltage components Udc and Uac of the voltage Us are chosen so that the metal salt formed by the ions of the solid electrolyte 4 with the gaseous components to be detected is again decomposed. The ion, current flowing between the electrodes is measured in dependence upon the voltage as applied. The concentration of the several gasses can be determined by known mathematical methods from the functional relation between the ion current and the voltage Us.
摘要翻译： PCT No.PCT / DE91 / 00313 Sec。 371日期：1992年9月28日 102（e）日期1992年9月28日PCT 1991年4月17日PCT PCT。第WO91 / 16624号公报日期为1991年10月31日。本发明涉及一种通过由三个电极1,2,3和固体电解质4组成的气体传感器来确定气体混合气体浓度的方法，其表面为固定电极。将由直流分量Udc和交流分量Uac组成的电压Us施加到至少两个电极，测量电极1和对电极2.Iu参照参考电极3进行控制。电压分量Udc和Uac 选择电压Us，使得由固体电解质4的离子形成的金属盐与待检测的气体成分再次分解。根据施加的电压来测量在电极之间流动的离子，电流。几种气体的浓度可以通过已知的数学方法从离子电流与电压Us之间的函数关系来确定。

2. 发明申请

US20100282958A1 METHOD FOR OPERATING AN FTIR SPECTROMETER, AND FTIR SPECTROMETER 审中-公开
标题翻译：操作FTIR光谱仪和FTIR光谱仪的方法
公开(公告)号：US20100282958A1
公开(公告)日：2010-11-11
申请号：US12784757
申请日：2010-05-21
申请人： Norbert WILL , Bernd Hielscher , Christoph Becker , Berthold Andres , Carsten Rathke
发明人： Norbert WILL , Bernd Hielscher , Christoph Becker , Berthold Andres , Carsten Rathke
IPC分类号： G01N21/35 , G12B13/00
CPC分类号： G01N21/276 , G01J3/28 , G01J3/42 , G01J2003/2866 , G01J2003/2879 , G01N21/03 , G01N21/05 , G01N21/13 , G01N21/274 , G01N21/31 , G01N21/35 , G01N21/3504 , G01N33/0004 , G01N33/0006 , G01N2021/0357 , G01N2021/0367 , G01N2021/3196 , G01N2021/3595
摘要： An FTIR (Fourier transformation infrared) spectrometer is disclosed, wherein a validation/calibration of the spectrometer can be carried out in cyclically recurring intervals. Using at least two temporarily available gases, a reference spectrum with a zero gas and an absorption spectrum with a calibration gas are recorded. Substitute gases can be used during validation of the spectrometer as gas components, the substitute gases simulating actual measured gas components with respect to metrological properties.
摘要翻译：公开了一种FTIR（傅里叶变换红外）光谱仪，其中可以循环重复的间隔进行光谱仪的验证/校准。使用至少两种临时可用的气体，记录具有零气体的参考光谱和具有校准气体的吸收光谱。在将光谱仪验证为气体组分时，替代气体可以被使用，替代气体相对于计量特性模拟实际测量的气体组分。

3. 发明授权

US5459075A Apparatus for measuring the total content of organic carbon and nitrogen in water 失效
标题翻译：用于测量水中有机碳和氮的总含量的装置
公开(公告)号：US5459075A
公开(公告)日：1995-10-17
申请号：US125410
申请日：1993-09-22
申请人： Walter Fabinski , Bernd Hielscher , Peter Schlau , Christian Wolff
发明人： Walter Fabinski , Bernd Hielscher , Peter Schlau , Christian Wolff
IPC分类号： G01N31/00 , G01N33/18 , G01N33/00 , G01N21/00
CPC分类号： G01N33/182 , G01N33/1846 , Y10T436/176152 , Y10T436/235
摘要： An apparatus for measuring the total content of organic carbon (TOC) and nitrogen (TN) in water. The TOC value is correctly determined as the sum of the liquid, dissolved, and solid substances of a specimen of the water. The apparatus includes a NDIR gas analyzer for simultaneously measuring the concentration of CO.sub.2 and NO gas components with a phase separator, a thermal reactor, a condenser, and two amplifiers for the pneumatic signals of the receivers with an indicator for the measured TOC and TN concentrations. The specimen is split into a gaseous part and a liquid part in the phase separator. The gaseous part which essentially contains the inorganic fraction of carbon, the TIC fraction, in the form of CO.sub.2 gas is cooled in a condenser until a substantial fraction of its water vapor content is separated in the condenser by condensation. The dried gaseous part is directed via the comparison vessels as comparison gas. The gaseous part exiting from the comparison vessels is returned to the liquid part of the specimen again in its entirety and oxidized together with the latter in a thermal reactor. The gas specimen which is formed in so doing is charged via the condenser with water vapor having the same temperature as the comparison gas and is fed to the measurement chambers of the vessels as measurement gas which contains the entire carbon dioxide fraction and the entire nitrogen oxide fraction of the gas specimen.
摘要翻译：一种用于测量水中有机碳（TOC）和氮（TN）的总含量的装置。 TOC值被正确地确定为水样品的液体，溶解和固体物质的总和。该装置包括一个NDIR气体分析仪，用于通过相分离器，热反应器，冷凝器和两个放大器同时测量CO2和NO气体组分的浓度，用于接收器的气动信号，并具有测量TOC和TN浓度的指标。样品在相分离器中分成气态部分和液体部分。基本上含有碳的无机部分的气体部分TIC部分以CO 2气体的形式在冷凝器中冷却，直到其水蒸汽含量的相当一部分在冷凝器中通过冷凝分离。干燥的气态部分通过比较容器作为比较气体引导。从比较容器中排出的气体部分全部返回到样品的液体部分，并在热反应器中与后者一起被氧化。这样形成的气体样品通过冷凝器与具有与比较气体相同温度的水蒸汽充入，并被供给至容器的测量室，作为包含整个二氧化碳馏分和整个氮氧化物的测量气体气体样本的分数。

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