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1. 发明申请

WO2012019674A2 HIGH TEMPERATURE LACTAM NEUTRALISATION 审中-公开
标题翻译：高温乳酸中和
公开(公告)号：WO2012019674A2
公开(公告)日：2012-02-16
申请号：PCT/EP2011003281
申请日：2011-07-01
申请人： DSM IP ASSETS BV , OEVERING HENDRIK , GUIT RUDOLF PHILIPPUS MARIA , BAUR HENRICUS ANNA CHRISTIAAN
发明人： OEVERING HENDRIK , GUIT RUDOLF PHILIPPUS MARIA , BAUR HENRICUS ANNA CHRISTIAAN
IPC分类号： C07D201/16
CPC分类号： C07D223/10 , C07D201/16
摘要： The invention relates to a method for preparing a lactam in a continuous process, comprising forming the lactam and ammonium sulphate by contacting a lactam sulphate contained in an acidic liquid with ammonia, during which forming of lactam heat of reaction is generated, which heat is partially or fully recovered, wherein ammonia is brought into contact with the acidic liquid as part of a liquid aqueous ammonia solution, and wherein the contacting takes place at a temperature of at least 120 °C, and wherein the average residence time at a temperature of at least 120 °C is at most 15 minutes, and wherein the ammonium sulphate remains dissolved in a liquid phase during said residence time.
摘要翻译：本发明涉及一种在连续方法中制备内酰胺的方法，包括通过使酸性液体中含有的内酰胺硫酸与氨接触来形成内酰胺和硫酸铵，在该反应期间产生反应的内酰胺热量，该热量部分地或完全回收，其中氨与液体氨水溶液的一部分与酸性液体接触，并且其中接触在至少120℃的温度下进行，并且其中在温度为至少120℃至多15分钟，其中硫酸铵在所述停留时间内保持溶于液相。

2. 发明申请

WO2005014520A1 PROCESS FOR THE CARBONYLATION OF CONJUGATED DIENES USING A PALLADIUM CATALYST SYSTEM 审中-公开
标题翻译：使用钯催化剂体系对共轭二烯进行羰基化的方法
公开(公告)号：WO2005014520A1
公开(公告)日：2005-02-17
申请号：PCT/EP2004/007059
申请日：2004-06-28
申请人： DSM IP ASSETS B.V. , SIELCKEN, Otto, Erik , BAUR, Henricus, Anna, Christiaan , TOTH, Imre
发明人： SIELCKEN, Otto, Erik , BAUR, Henricus, Anna, Christiaan , TOTH, Imre
IPC分类号： C07C67/38
CPC分类号： C07C67/38 , C07C69/533
摘要： A process is provided, in particular a continuous process for the carbonylation of butadiene by reacting the butadiene with carbon monoxide and a hydroxyl group-containing compound in the presence of a palladium catalyst system in a reaction zone to form a reaction mixture, said catalyst system comprising (a) a source of palladium cations, (b) a mono-, bi- or multidentate phosphine ligand, containing at least one phosphorus atom which is directly bound to two or three aliphatic carbon atoms, as process ligand to produce a palladium-phosphine ligand complex catalyst, and (c) a source of anions, said process ligand (b) containing the moiety shown in formula (I), wherein A 1 and A 2 each represent an aliphatic carbon atom which can be connected to one or more aliphatic or aromatic carbon atoms or both A 1 and A 2 are part of an at least 5-membered ring including the phosphorus atom, and X represents an aliphatic or aromatic carbon atom which can be connected to one or more aliphatic or aromatic carbon atoms or X is part of an organic bridging group connecting another identically or differently substituted phosphorus atom, and said source of anions (c) containing a carboxylic acid and, optionally, halide ions, wherein said process ligand is fed continuously or periodically to the process as ligand make-up at a temperature 50°C or lower.
摘要翻译：提供了一种方法，特别是通过在反应区中在钯催化剂体系的存在下使丁二烯与一氧化碳和含羟基的化合物反应以形成反应混合物来进行丁二烯的羰基化的连续方法，所述催化剂体系包括（a）钯阳离子源，（b）单，双或多齿膦配体，其含有至少一个直接键合到两个或三个脂族碳原子上的磷原子作为过程配体以产生钯 - 膦配体配合物催化剂，和（c）阴离子源，所述方法配体（b）含有式（I）所示的部分，其中A 1和A 2各自表示可连接的脂族碳原子至一个或多个脂族或芳族碳原子，或者A 1和A 2均为包括磷原子的至少5元环的一部分，X表示可连接到一个或多个的脂族或芳族碳原子或更多脂肪族o R是芳族碳原子，或X是连接另一相同或不同取代的磷原子的有机桥连基团的一部分，以及含有羧酸和任选的卤素离子的所述阴离子源（c），其中所述方法配体被连续或周期性地进料在50℃或更低的温度下作为配体化妆。

3. 发明申请

WO2013053377A1 HIGH TEMPERATURE LACTAM NEUTRALISATION 审中-公开
标题翻译：高温乳酸中和
公开(公告)号：WO2013053377A1
公开(公告)日：2013-04-18
申请号：PCT/EP2011/067650
申请日：2011-10-10
申请人： DSM IP ASSETS B.V. , OEVERING, Hendrik , GUIT, Rudolf Philippus Maria , BAUR, Henricus Anna Christiaan
发明人： OEVERING, Hendrik , GUIT, Rudolf Philippus Maria , BAUR, Henricus Anna Christiaan
IPC分类号： C07D201/04 , C07D201/16 , C07D223/10
CPC分类号： C07D201/16 , C07D201/04 , C07D223/10
摘要： The invention relates to a method for preparing a lactam in a continuous process, comprising forming the lactam and ammonium sulphate by contacting a lactam sulphate contained in an acidic liquid with ammonia, during which forming of lactam heat of reaction is generated, which heat is partially or fully recovered, wherein ammonia is brought into contact with the acidic liquid as part of a liquid aqueous ammonia solution, and wherein the contacting takes place at a temperature of at least 120 °C, and wherein the average residence time at a temperature of at least 120 °C is at most 15 minutes, and wherein the ammonium sulphate remains dissolved in a liquid phase during said residence time.
摘要翻译：本发明涉及一种在连续方法中制备内酰胺的方法，包括通过使酸性液体中含有的内酰胺硫酸与氨接触形成内酰胺和硫酸铵，在此期间产生反应的内酰胺热量，该热量部分地或完全回收，其中氨与液体氨水溶液的一部分与酸性液体接触，并且其中接触在至少120℃的温度下进行，并且其中在温度为至少120℃至多为15分钟，其中硫酸铵在所述停留时间期间保持溶于液相。

4. 发明申请

WO2012019674A3 HIGH TEMPERATURE LACTAM NEUTRALISATION 审中-公开
公开(公告)号：WO2012019674A3
公开(公告)日：2012-02-16
申请号：PCT/EP2011/003281
申请日：2011-07-01
申请人： DSM IP Assets B.V. , OEVERING, Hendrik , GUIT, Rudolf Philippus Maria , BAUR, Henricus Anna Christiaan
发明人： OEVERING, Hendrik , GUIT, Rudolf Philippus Maria , BAUR, Henricus Anna Christiaan
IPC分类号： C07D201/16
摘要： The invention relates to a method for preparing a lactam in a continuous process, comprising forming the lactam and ammonium sulphate by contacting a lactam sulphate contained in an acidic liquid with ammonia, during which forming of lactam heat of reaction is generated, which heat is partially or fully recovered, wherein ammonia is brought into contact with the acidic liquid as part of a liquid aqueous ammonia solution, and wherein the contacting takes place at a temperature of at least 120 °C, and wherein the average residence time at a temperature of at least 120 °C is at most 15 minutes, and wherein the ammonium sulphate remains dissolved in a liquid phase during said residence time.

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