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    • 9. 发明申请
    • SOLUTION POLYMERIZED HALOGENATED POLYESTERS
    • 溶液聚合的氢化聚酯
    • WO1979000071A1
    • 1979-02-22
    • PCT/US1978000048
    • 1978-07-25
    • CELANESE CORP
    • CELANESE CORPSTACKMAN RSAKOWITZ MROSENTHAL A
    • C08G63/22
    • C08G63/81C08G63/6824
    • A process for preparing certain halogenated aromatic polyesters having a predetermined molecular weight is provided. Such polyesters are prepared by solution polymerization of an appropriate bisphenol and diacid halide wherein the diacid halide is added to a solution containing the bisphenol until the viscosity of the resulting polymer containing solution reaches a predetermined solution viscosity limit at which time the further addition of diacid halide is terminated. The solution limit is indicative of the attainment of said predetermined molecular weight. The identification of said solution viscosity limit is achieved by a feedback mechanism wherein the viscosity of the polymer containing solution is monitored or sensed during or after the addition of the diacid halide to the bisphenol containing solution.
    • 提供了制备具有预定分子量的某些卤代芳族聚酯的方法。 这种聚酯通过适当的双酚和二卤化物的溶液聚合制备,其中将二酸卤化物加入到含有双酚的溶液中,直到得到的含聚合物溶液的粘度达到预定的溶液粘度极限,此时进一步加入二酰卤 被终止。 溶液极限表示达到所述预定分子量。 所述溶液粘度极限的鉴定通过反馈机制来实现,其中在向含双酚的溶液中加入二酸卤化物期间或之后监测或感测含聚合物的溶液的粘度。