基本信息:
- 专利标题: POLYPROPYLENE COMPOSITIONS
- 申请号:PCT/EP2021/078499 申请日:2021-10-14
- 公开(公告)号:WO2022079190A1 公开(公告)日:2022-04-21
- 发明人: COUSTHAM, Thomas , STANDAERT, Alain , VANTOMME, Aurélien , SIGWALD, Armelle
- 申请人: TOTALENERGIES ONE TECH BELGIUM
- 申请人地址: Zone Industrielle C
- 专利权人: TOTALENERGIES ONE TECH BELGIUM
- 当前专利权人: TOTALENERGIES ONE TECH BELGIUM
- 当前专利权人地址: Zone Industrielle C
- 代理机构: GARCIA MARTIN, Margarita
- 优先权: EP20201895.8 2020-10-14
- 主分类号: C08L23/14
- IPC分类号: C08L23/14 ; C08F210/06 ; C08F4/659 ; C08F4/6592
摘要:
The invention relates to a polypropylene composition comprising:(a) a first metallocene-catalyzed polypropylene (RPP-A) which is homopolymer, or a random copolymer of propylene and of a co-monomer; and (b) a second metallocene-catalyzed polypropylene (RPP-B) which is a random copolymer of propylene and of a co-monomer; wherein said polypropylene composition has:- a total co-monomer content of at least 1.1 % by weight relative to the total weight of said polypropylene composition, as determined by 13C NMR analysis, said co-monomer being an alpha-olefin different from propylene;- a melting temperature Tm of at least 130 °C, measured by DSC; - a crystallization temperature Tc of at least 95.0 °C, measured by DSC; - a ratio of weight average molecular weight (Mw) to number average molecular weight (Mn) [Mw/Mn] of at least 4.50;- a ratio of z-average molecular weight (Mz) to weight average molecular weight (Mw) [Mz/Mw] of at least 2.10; and- a co-monomer distribution ratio R(Mz)/R(Mn) higher than 0.995, wherein R(Mz) is the ratio at Mz of the IR signal measured at 2959 cm-1 on the signal at 2928 cm-1, and R(Mn) is the ratio at Mn of the IR signal measured at 2959 cm-1 on the signal at 2928 cm-1, as determined by IR-detected gel permeation chromatography and- a xylene soluble content (XS) of at most 3.0 % by weight.The present invention also relates to a process for the preparation of said polypropylene composition. The present invention also relates to an article comprising said polypropylene composition.
IPC结构图谱:
C | 化学;冶金 |
--C08 | 有机高分子化合物;其制备或化学加工;以其为基料的组合物 |
----C08L | 高分子化合物的组合物 |
------C08L21/00 | 未指定的橡胶的组合物 |
--------C08L23/02 | .未用化学后处理改性的 |
----------C08L23/04 | ..乙烯的均聚物或共聚物 |
------------C08L23/14 | ...丙烯的共聚物 |