基本信息:
- 专利标题: CATALYST SYSTEM AND PROCESS FOR THE PRODUCTION OF POLYETHYLENES.
- 专利标题(中):催化剂体系和生产聚乙烯的方法。
- 申请号:PCT/EP2016/055181 申请日:2016-03-10
- 公开(公告)号:WO2016150725A1 公开(公告)日:2016-09-29
- 发明人: MEPPELDER, Geert, Johannes, Marinus , KRUCK, Johannes, Julian, Matthias , JANSSEN, Eric, Johannes, Cornelia , CHAN, Robert, Lap, Key
- 申请人: SABIC GLOBAL TECHNOLOGIES B.V.
- 申请人地址: Plasticslaan 1 4612 PX Bergen op Zoom NL
- 专利权人: SABIC GLOBAL TECHNOLOGIES B.V.
- 当前专利权人: SABIC GLOBAL TECHNOLOGIES B.V.
- 当前专利权人地址: Plasticslaan 1 4612 PX Bergen op Zoom NL
- 代理机构: SABIC INTELLECTUAL PROPERTY GROUP
- 优先权: EP15160476.6 20150324
- 主分类号: C08F4/649
- IPC分类号: C08F4/649 ; C08F210/16 ; C08F2/00
摘要:
The present invention relates to a catalyst system for the production of polyethylene comprising: I) the reaction product obtained by reacting a) a hydrocarbon solution comprising: i. a magnesium-containing compound selected from an organic oxygen-containing magnesium compound and/or a halogen-containing magnesium compound; and ii. an organic oxygen-containing titanium compound wherein the molar ratio of magnesium: titanium is lower than 3:1; and b) an organo aluminium halide having the formula AlR n X 3-n in which R is a hydrocarbon moiety containing 1-10 carbon atoms, X is a halogen and 0 3 , in which R' is a hydrocarbon moiety containing 1-10 carbon atoms; and III) one or more of an electron donor selected from the group of 1,2-dialkoxy hydrocarbon compounds wherein the molar ratio of supplied organo aluminium halide I)b) to supplied titanium in I) a) in the preparation of I) is between 5.0 and 7.0; and the molar ratio of the electron donor III) to the titanium present in the reaction product I) is between 0.05 and 0.40 The production of polyethylene using said catalyst system results in a reduction of formation of ethane and a reduction of the hexane-extractable content of the polyethylene.
摘要(中):
本发明涉及用于生产聚乙烯的催化剂体系,其包括:I)通过使a)烃溶液反应获得的反应产物,其包含: 选自含有机氧的镁化合物和/或含卤素的镁化合物的含镁化合物; 和ii。 其中镁:钛的摩尔比低于3:1的有机含氧钛化合物; 和b)具有式AlRnX3-n的有机铝卤化物,其中R是含有1-10个碳原子的烃部分,X是卤素且0
IPC结构图谱:
C | 化学;冶金 |
--C08 | 有机高分子化合物;其制备或化学加工;以其为基料的组合物 |
----C08F | 仅用碳—碳不饱和键反应得到的高分子化合物 |
------C08F4/00 | 聚合催化剂 |
--------C08F4/42 | .金属;金属氢化物;金属有机化合物;及其作为催化剂母体的用途 |
----------C08F4/44 | ..选自轻金属、锌、镉、汞、铜、银、金、硼、镓、铟、铊、稀土元素或锕族元素 |
------------C08F4/60 | ...与高熔点金属、铁族金属、铂族金属、锰、锝、铼或它们的化合物在一起 |
--------------C08F4/607 | ....含有一种特殊的非金属或不含金属化合物的催化剂 |
----------------C08F4/627 | .....催化剂含有一种特殊的非金属或不含金属的化合物 |
------------------C08F4/647 | ......催化剂含有一种特殊的非金属或不含金属的化合物 |
--------------------C08F4/649 | .......有机物的 |