基本信息:
- 专利标题: PROCESS FOR CONTINUOUSLY PREPARING DI-C1-3-ALKYL SUCCINATES
- 专利标题(中):连续制备DI-C 3-烷基琥珀酸酯的方法
- 申请号:PCT/EP2014/059278 申请日:2014-05-07
- 公开(公告)号:WO2014180871A1 公开(公告)日:2014-11-13
- 发明人: DEMMING, Stefanie , THOTLA, Suman , WITTENBERG, Jens , IFFLAND, Gabriele , BRÜGGEMANN, Till, Christian , HOELZL, Yvonne , SIEGEL, Wolfgang , FREYER, Stephan
- 申请人: BASF SE
- 申请人地址: 67056 Ludwigshafen DE
- 专利权人: BASF SE
- 当前专利权人: BASF SE
- 当前专利权人地址: 67056 Ludwigshafen DE
- 代理机构: FÉAUX DE LACROIX, Stefan
- 优先权: EP13167052.3 20130508
- 主分类号: C07C67/08
- IPC分类号: C07C67/08
摘要:
The invention relates to a process for continuously preparing di-C 1-3 -alkyl succinates by reacting succinic acid with an C 1-3 -alkanol in the presence of a fixed-bed heterogeneous acidic esterification catalyst in a tubular reactor at a temperature in the range of from 60 to 100°C, wherein a mixture, comprising succinic acid, C 1-3 -alkanol, mono-C 1-3 -alkyl succinate, di-C 1-3 -alkyl succinate and water, is formed in a mixing stage and fed to the entrance of the tubular reactor, and wherein 5 to 75% of the outlet flow rate of the tubular reactor are recycled directly to the mixing stage as a recycle stream, and the molar ratio of C 1-3 -alkanol to succinic acid added to the mixing zone, and not including the C 1-3 -alkanol and succinic acid at the recycle stream, being in the range of from 2.0 to 9.5. The invention furthermore relates to a process for separating the reactor effluent of an esterification of succinic acid with an C 1-3 -alkanol to give di-C1-3-alkyl succinates by distillation, wherein the separation is performed in a divided wall column in which C 1-3 -alkanol and water are removed in a top draw of the column, di-C 1-3 -alkyl succinate is removed in a side draw of the column, and wherein mono-C 1-3 -alkyl succinate and succinic acid are removed in a bottom draw of the column.
摘要(中):
本发明涉及一种连续制备二-C1-烷基琥珀酸盐的方法,该方法是在固定床非均相酸性酯化催化剂存在下,在管式反应器中在一定温度范围内使琥珀酸与C 1-3烷醇反应 为60〜100℃,其中在混合阶段中形成包含琥珀酸,C 1-3链烷醇,琥珀酸单C 1-3烷基酯,琥珀酸二-C 1-3烷基酯和水的混合物,并加入 到管式反应器的入口,并且其中管式反应器的出口流量的5%至75%作为循环流直接循环到混合阶段,并且将C 1-3烷醇与琥珀酸的摩尔比加到 混合区,并且在再循环流中不包括C 1-3烷醇和琥珀酸,其范围为2.0-9.5。 本发明还涉及一种将琥珀酸酯化为C 3-链烷醇的反应器流出物分离以通过蒸馏得到二-C1-烷基琥珀酸酯的方法,其中分离是在分隔壁塔中进行的,其中在 在柱的顶部萃取中除去C 1-3链烷醇和水,在柱的侧馏分中除去琥珀酸二-C1--3烷基酯,并且其中除去C 1 -C 3烷基琥珀酸酯和琥珀酸单 在列的底部绘制。