基本信息:
- 专利标题: HETEROGENEOUS IN-REACTOR POLYMER BLENDS
- 专利标题(中):异构反应器聚合物共混
- 申请号:PCT/US2009068116 申请日:2009-12-15
- 公开(公告)号:WO2010075106A3 公开(公告)日:2010-09-23
- 发明人: DEGRACIA CARLOS U , SQUIRE KEVIN R , JIANG PEIJUN , DEKMEZIAN ARMENAG , POOLE BEVERLY JEAN , GARCIA-FRANCO CESAR A
- 申请人: EXXONMOBIL CHEM PATENTS INC , DEGRACIA CARLOS U , SQUIRE KEVIN R , JIANG PEIJUN , DEKMEZIAN ARMENAG , POOLE BEVERLY JEAN , GARCIA-FRANCO CESAR A
- 专利权人: EXXONMOBIL CHEM PATENTS INC,DEGRACIA CARLOS U,SQUIRE KEVIN R,JIANG PEIJUN,DEKMEZIAN ARMENAG,POOLE BEVERLY JEAN,GARCIA-FRANCO CESAR A
- 当前专利权人: EXXONMOBIL CHEM PATENTS INC,DEGRACIA CARLOS U,SQUIRE KEVIN R,JIANG PEIJUN,DEKMEZIAN ARMENAG,POOLE BEVERLY JEAN,GARCIA-FRANCO CESAR A
- 优先权: US33525208 2008-12-15
- 主分类号: C08L23/10
- IPC分类号: C08L23/10 ; C08L23/04
摘要:
An in-reactor polymer blend comprises (a) a propylene-containing first polymer; and (b) an ethylene-containing second polymer such that the polymer blend comprises between about 50 wt% and about 80 wt% units derived from ethylene and between about 50 wt% and about 20 wt% units derived from propylene. The blend is substantially free of dienes and the content of ethylene in the second polymer in the form of ethylene-ethylene-ethylene triads is at least 40%. The second polymer contains at least 0.1 branch having 8 or more carbon atoms per 10,000 carbons. In addition, the blend has a strain hardening index of at least 1.8, a shear thinning slope in the plot of log(dynamic viscosity) versus log(frequency) of less than -0.2 and exhibits at least two peaks when subjected to Differential Scanning Calorimetry (first melt) corresponding to a first melting point of at least 1500C and a second melting point of at least 400C such that the difference between the first and second melting temperatures is at least 200C.
摘要(中):
反应器内聚合物共混物包含(a)含丙烯的第一聚合物; 和(b)含乙烯的第二聚合物,使得聚合物共混物包含衍生自乙烯的约50重量%至约80重量%的单元和衍生自丙烯的约50重量%至约20重量%的单元。 共混物基本上不含二烯,乙烯 - 乙烯 - 乙烯三单元组形式的第二聚合物中的乙烯含量至少为40%。 第二聚合物含有至少0.1个分支,每10,000个碳原子具有8个或更多个碳原子。 此外,共混物的应变硬化指数为至少1.8,对数(动态粘度)对log(频率)的曲线图中的剪切变稀斜率小于-0.2,并且当进行差示扫描量热法时显示出至少两个峰 (第一熔体),其对应于至少150℃的第一熔点和至少40℃的第二熔点,使得第一和第二熔融温度之间的差异为至少20℃。
IPC结构图谱:
C | 化学;冶金 |
--C08 | 有机高分子化合物;其制备或化学加工;以其为基料的组合物 |
----C08L | 高分子化合物的组合物 |
------C08L21/00 | 未指定的橡胶的组合物 |
--------C08L23/02 | .未用化学后处理改性的 |
----------C08L23/10 | ..丙烯的均聚物或共聚物 |