基本信息:
- 专利标题: 芳香族化合物及びスルホン化ポリアリーレン系重合体
- 专利标题(英):Aromatic compound and sulfonated polyarylene polymer
- 专利标题(中):芳香化合物和磺化聚亚烷基聚合物
- 申请号:PCT/JP2007/058856 申请日:2007-04-24
- 公开(公告)号:WO2007125919A1 公开(公告)日:2007-11-08
- 发明人: 山川 芳孝 , 今野 洋助 , 梅原 輝彦
- 申请人: JSR株式会社 , 山川 芳孝 , 今野 洋助 , 梅原 輝彦
- 申请人地址: 〒1040045 東京都中央区築地五丁目6番10号 Tokyo JP
- 专利权人: JSR株式会社,山川 芳孝,今野 洋助,梅原 輝彦
- 当前专利权人: JSR株式会社,山川 芳孝,今野 洋助,梅原 輝彦
- 当前专利权人地址: 〒1040045 東京都中央区築地五丁目6番10号 Tokyo JP
- 代理机构: 鈴木 俊一郎
- 优先权: JP2006-121081 20060425
- 主分类号: C08G85/00
- IPC分类号: C08G85/00 ; C07C50/30 ; C07C255/54 ; C08G65/40 ; H01B1/06 ; H01M8/02 ; H01M8/10
摘要:
Disclosed is a sulfonated polymer having excellent workability and excellent methanol resistance. More specifically, disclosed is an aromatic compound represented by the general formula (1): (1) wherein A, D and E independently represent at least one structure selected from the group consisting of a direct bond, -O-, -S-, -CO-, -SO 2 -, -SO-, -CONH-, -COO-, -(CF 2 ) f - [wherein f represents an integer ranging from 1 to 10], -(CH 2 ) h - [wherein h represents an integer ranging from 1 to 10], -CR' 2 - [wherein R' represents an aliphatic hydrocarbon group, an aromatic hydrocarbon group or a halogenated hydrocarbon group], a cyclohexylidene group, and a fluorenylidene group; B's independently represent an oxygen atom or a sulfur atom; X represents an atom or group selected from a halogen atom other than a fluorine atom, -OSO 2 CH 3 and -OSO 2 CF 3 ; R 1 to R 28 independently represent at least one atom or group selected from the group consisting of a hydrogen atom, a fluorine atom, an alkyl group, a partially or entirely halogenated alkyl group, an allyl group, an aryl group, a nitro group and a nitryl group; l and o independently represent an integer ranging from 0 to 4; m represents an integer ranging from 1 to 4; q represents an integer equal to or greater than 2; and n and p independently represent a compositional ratio of each unit, independently have a value ranting from 0 to 1, and satisfy the following equation: n+p = 1, provided that n has a value other than 0.
摘要(中):
公开了具有优异的加工性和优异的耐甲醇性的磺化聚合物。 更具体地,公开了由通式(1)表示的芳族化合物:(1)其中A,D和E独立地表示至少一种选自直接键,-O - , - S-, -CO - , - SO 2 - , - SO - , - CONH - , - CO-, - (CF 2 H) - [ 其中f表示1至10的整数], - (CH 2 CH 2)h - [其中h表示1至10的整数],-CR' 其中R'表示脂族烃基,芳族烃基或卤代烃基],亚环己基和亚芴基; B独立地表示氧原子或硫原子; X表示选自除氟原子以外的卤素原子的原子或基团,-OSO 2 CH 3和-OSO 2 sub> CF 3 SUB>; R 1至R 28独立地表示至少一个选自氢原子,氟原子,烷基,部分或完全卤化的原子或基团 烷基,烯丙基,芳基,硝基和硝基; l和o独立地表示0至4的整数; m表示1〜4的整数; q表示等于或大于2的整数; 并且n和p独立地表示每个单元的组成比,独立地具有0至1的值,并且满足以下等式:n + p = 1,条件是n具有不同于0的值。