发明申请
WO2006009662A2 METHODS FOR RECYCLING CATALYST COMPOSITIONS FOR AROMATIC RING HALOGENATION
审中-公开
基本信息:
- 专利标题: METHODS FOR RECYCLING CATALYST COMPOSITIONS FOR AROMATIC RING HALOGENATION
- 专利标题(中):回收环氧化合物催化剂组合物的方法
- 申请号:PCT/US2005/020788 申请日:2005-06-13
- 公开(公告)号:WO2006009662A2 公开(公告)日:2006-01-26
- 发明人: GANESAN, Balakrishnan , NADKARNI, Pradeep, Jeevaji , COLBORN, Robert, Edgar , HANCU, Dan
- 申请人: GENERAL ELECTRIC COMPANY , GANESAN, Balakrishnan , NADKARNI, Pradeep, Jeevaji , COLBORN, Robert, Edgar , HANCU, Dan
- 申请人地址: 1 River Road, Schenectady, NY 12345 US
- 专利权人: GENERAL ELECTRIC COMPANY,GANESAN, Balakrishnan,NADKARNI, Pradeep, Jeevaji,COLBORN, Robert, Edgar,HANCU, Dan
- 当前专利权人: GENERAL ELECTRIC COMPANY,GANESAN, Balakrishnan,NADKARNI, Pradeep, Jeevaji,COLBORN, Robert, Edgar,HANCU, Dan
- 当前专利权人地址: 1 River Road, Schenectady, NY 12345 US
- 代理机构: WINTER, Catherine, J. et al.
- 优先权: US10/870,352 20040616
- 主分类号: C07C17/00
- IPC分类号: C07C17/00
摘要:
A method for recovering and reusing a ring-halogenation catalyst comprises: (A) contacting an aromatic compound with chlorine or bromine in the presence of a catalyst composition, where the catalyst composition comprises at least one salt comprising a Group 4 - 13 metal, a lanthanide metal, or an actinide metal; and at least one organic counterion derived from an organic acid having a pKa relative to water of 0 or greater; and at least one organic sulfur compound; to form a first product mixture comprising a monochloro or a monobromo aromatic compound and a Group 4 - 13 metal halide, a lanthanide metal halide or an actinide metal halide; (B) separating the metal halide from the first product mixture; and (C) contacting at least a portion of the metal halide and an aromatic compound with chlorine or bromine, and at least one organic sulfur compound; to form a second product mixture comprising a monochloro or a monobromo aromatic compound and a Group 4 - 13 metal halide, a lanthanide metal halide or an actinide metal halide.ving a pKa relative to water of 0 or greater; and at least one organic sulfur compound.
摘要(中):
回收和再利用环卤化催化剂的方法包括:(A)在催化剂组合物存在下使芳族化合物与氯或溴接触,其中催化剂组合物包含至少一种包含第4-13族金属的盐, 镧系金属或锕系金属; 以及衍生自相对于水的pKa为0以上的有机酸的至少一种有机抗衡离子; 和至少一种有机硫化合物; 以形成包含一氯或一溴芳族化合物和第4-13族金属卤化物,镧系金属卤化物或锕系金属卤化物的第一产物混合物; (B)将金属卤化物与第一产物混合物分离; 和(C)使金属卤化物和芳族化合物的至少一部分与氯或溴接触,和至少一种有机硫化合物; 以形成包含单氯或一溴芳族化合物和第4-13族金属卤化物,镧系元素金属卤化物或锕系金属卤化物的第二产物混合物,相对于0或更大的水,得到pKa; 和至少一种有机硫化合物。