基本信息:
- 专利标题: METHOD FOR THE CATALYTIC PRODUCTION OF AMMONIA FROM SYNTHESIS GAS
- 专利标题(中):合成氨催化生产氨的方法
- 申请号:PCT/EP0201609 申请日:2002-02-15
- 公开(公告)号:WO02079088A3 公开(公告)日:2002-11-28
- 发明人: UNGAR GERT , UNGAR JUERG DIETER , UNGAR SYBILLE
- 申请人: MG TECHNOLOGIES AG , UNGAR GERT , UNGAR JUERG DIETER , UNGAR SYBILLE
- 专利权人: MG TECHNOLOGIES AG,UNGAR GERT,UNGAR JUERG DIETER,UNGAR SYBILLE
- 当前专利权人: MG TECHNOLOGIES AG,UNGAR GERT,UNGAR JUERG DIETER,UNGAR SYBILLE
- 优先权: DE10116150 2001-03-31
- 主分类号: B01J8/04
- IPC分类号: B01J8/04 ; C01C1/04
摘要:
Ammonia is produced from a synthesis gas comprising nitrogen and hydrogen on a particulate catalyst in at least one reactor at pressures in the range of from 50 to 300 bar and temperatures in the range of 100 to 600 DEG C. A product mixture containing NH3 vapour is withdrawn from the reactor and cooled, thus condensing and separating out the ammonia. A circulation gas is thus produced, which is mixed with fresh synthesis gas and then returned to the reactor as synthesis gas. Unreacted synthesis gas is fed through a first catalytic bed with no cooling tubes and then, as part-reacted synthesis gas, with a NH3 content of 5 to 20 vol. %, through a heat exchanger as the heating fluid. Part-reacted synthesis gas is fed through at least one further catalyst bed, with cooling tubes running therethrough. Unreacted synthesis gas is fed through the cooling tubes of the further catalytic bed as cooling gas and cooling gas, heated to 300 to 500 DEG C, is fed to the first catalytic bed. The cooling tubes and the further catalytic bed flow co-currently.
摘要(中):
氨在至少一个反应器中在粒状催化剂上由含有氮气和氢气的合成气在50-300巴的压力和100-600℃的温度范围内制备 从反应器中取出含NH 3蒸汽的产物混合物,冷却,同时冷凝出氨并分离。 这产生了再循环气体,新鲜合成气与其混合并且其中再循环气体作为合成气被再循环到反应器中。 未反应的合成气通过第一传递,自由冷却管,并随后根据催化剂床部分地通过热交换器的NH 3含量的5〜20%(体积)作为加热流体反应的合成气。 部分反应的合成气通过至少一个由冷却管穿过的另外的催化剂床。 未反应的合成气作为冷却气体通过另一催化剂床的冷却管并加热至300-500℃,将冷却气体通入第一催化剂床。 冷却管和另外的催化剂床以直流方式流过。
IPC结构图谱:
B | 作业;运输 |
--B01 | 一般的物理或化学的方法或装置 |
----B01J | 化学或物理方法,例如,催化作用、胶体化学;其有关设备 |
------B01J8/00 | 在有流体和固体颗粒的情况下所进行的一般化学或物理的方法;这些方法所用的装置 |
--------B01J8/02 | .用静止颗粒,例如,在固定床内 |
----------B01J8/04 | ..流体连续通过两个或更多的床 |