发明申请
WO00018728A1 METHOD OF QUENCHING GASEOUS ACRYLONITRILE AND HYDROGEN CYANIDE PRODUCT STREAM
审中-公开
基本信息:
- 专利标题: METHOD OF QUENCHING GASEOUS ACRYLONITRILE AND HYDROGEN CYANIDE PRODUCT STREAM
- 专利标题(英):Method of quenching gaseous acrylonitrile and hydrogen cyanide product stream
- 专利标题(中):气相丙烯腈和氢化氰化物产品流程的方法
- 申请号:PCT/US1999/022484 申请日:1999-09-28
- 公开(公告)号:WO00018728A1 公开(公告)日:2000-04-06
- 主分类号: B01J10/00
- IPC分类号: B01J10/00 ; C07C253/24 ; C07C253/34 ; C07C255/08
摘要:
The present invention provides an improvement in a process and apparatus for manufacturing acrylonitrile by the vapor phase ammoxidation of a hydrocarbon. The invention comprises contacting the gaseous product stream with a quench fluid in a reverse jet scrubber. The quenching fluid is injected counter-current to the gas flow, and the gas velocity is sufficient to reverse the flow direction of the water, thereby forming a standing wave or froth zone wherein the quench is rapidly achieved. The quench fluid may be obtained from many sources, but is preferably obtained from a waste process stream emanating from a subsequent recovery or purification step. The quench fluid may contain acid to facilitate removal of ammonia from the gas stream. The quench fluid that is not vaporized may be recirculated. Impurities and contaminants may be removed from the quench fluid prior to recycle. In a most preferred embodiment, the quench fluid is not cooled during recirculation, and the cooling process is essentially adiabatic, with the sensible heat of the hot gaseous stream being converted to latent heat in the form of vapor.
摘要(中):
本发明提供了通过烃的气相氨氧化制备丙烯腈的方法和装置的改进。 本发明包括使气态产物流与反向喷射洗涤器中的骤冷流体接触。 淬火流体与气流逆流注入,气体流速足以反转水的流动方向,从而形成驻波或泡沫区,其中快速实现骤冷。 骤冷流体可以从许多来源获得,但优选地从随后的回收或纯化步骤发出的废物流中获得。 骤冷流体可含有酸,以便于从气流中除去氨。 未蒸发的骤冷液体可以再循环。 杂质和污染物可以在循环之前从骤冷流体中除去。 在最优选的实施方案中,骤冷流体在再循环过程中不被冷却,并且冷却过程基本上是绝热的,热气流的显热转化为蒸气形式的潜热。
IPC结构图谱:
B | 作业;运输 |
--B01 | 一般的物理或化学的方法或装置 |
----B01J | 化学或物理方法,例如,催化作用、胶体化学;其有关设备 |
------B01J10/00 | 不存在固体颗粒的情况下,使液体与气体介质起反应的一般化学方法或其专用设备 |