基本信息:
- 专利标题： HYDROLYZABLE AND POLYMERIZABLE OR ADDITION-POLYMERIZABLE SILANES
- 专利标题（中）：水解和可聚合的或可 polyaddable硅烷
- 申请号：PCT/DE1996001216 申请日：1996-07-05
- 公开(公告)号：WO1997002272A1 公开(公告)日：1997-01-23
- 发明人： FRAUNHOFER-GESELLSCHAFT ZUR FÖRDERUNG DER ANGEWANDTEN FORSCHUNG E.V.
- 申请人： FRAUNHOFER-GESELLSCHAFT ZUR FÖRDERUNG DER ANGEWANDTEN FORSCHUNG E.V. , WOLTER, Herbert , STORCH, Werner
- 专利权人： FRAUNHOFER-GESELLSCHAFT ZUR FÖRDERUNG DER ANGEWANDTEN FORSCHUNG E.V.,WOLTER, Herbert,STORCH, Werner
- 当前专利权人： FRAUNHOFER-GESELLSCHAFT ZUR FÖRDERUNG DER ANGEWANDTEN FORSCHUNG E.V.,WOLTER, Herbert,STORCH, Werner
- 优先权： DE195 19950706
- 主分类号： C07F07/18
- IPC分类号： C07F07/18
摘要：
The invention concerns hydrolyzable and polymerizable or addition-polymerizable silanes, a process for their preparation and their use for producing silicic acid (hetero)polycondensates or polymers. The silanes according to the invention have the general formula (I) in which the groups and indices are identical or different and have the following meanings: R = hydrogen, R -R -R -SiXxR 3-x, carboxyl, alkyl, alkenyl, aryl, alkylaryl or arylalkyl; R = alkylene, arylene, arylene alkylene or arylene alkylene; R = alkylene, arylene, arylene alkylene or arylene alkylene; R = alkyl, alkenyl, aryl, alkylaryl or arylalkyl; R = -(CHR -CHR )n-, in which n = 0 or 1, -CHR -CHR -S-R -, -CO-S-R -, -CHR -CHR -NR -R -, -Y-CS-NH-R -, -S-R , -Y-CO-NH-R -, -CO-O-R -, -Y-CO-C2H3(COOH)-R -, -Y-CO-C2H3(OH)-R - or -CO-NR -R -; R = alkylene, arylene, arylene alkylene or arylene alkylene; R = hydrogen, alkyl or aryl with 1 to 10 carbon atoms; R = hydrogen, alkyl, alkenyl, aryl, alkylaryl or arylalkyl; X = hydrogen, halogen, hydroxy, alkoxy, acyloxy, alkylcarbonyl, alkoxycarbonyl or NR"2, in which R" = hydrogen, alkyl or aryl; Y = -O-, -S- or -NR -; Z = -O- or -(CHR )m-, in which m = 1 or 2; a = 1, 2 or 3, with b = 1 when a = 2 or 3; b = 1, 2 or 3, with a = 1 when b = 2 or 3; c = 1 to 6; x = 1, 2 or 3; and a+x = 2, 3 or 4.
摘要（中）：
本发明涉及水解性和可聚合的或polyaddable硅烷，其制备方法及其用于生产硅酸（杂）缩聚物或聚合物的用途。 新颖的硅烷具有通式（I），其中基团和指数是相同的或不同的并且是以下含义：R =氢，R <2> -R <1> -R <4> -SiXxR <3> 3 -x，羧基，烷基，烯基，芳基，烷芳基或芳基烷基; [R <1> =亚烷基，亚芳基，亚芳基亚或亚芳基亚; [R <2> =亚烷基，亚芳基，亚芳基亚或亚芳基亚; [R <3> =烷基，烯基，芳基，烷芳基或芳基烷基; [R <4> = - （CHR <6> -CHR <6>）n - ，其中n = 0或1，-CHR <6> -CHR <6> -SR <5> - ， - CO-SR <5 >，-CHR <6> -CHR <6>是-NR <6> -R <5> - ，-Y-CS-NH-R <5> - ，-SR <5>，-Y-CO-NH- [R <5> - ， - CO-或<5> - ，-Y-CO-C2H3（COOH）-R <5> - ，-Y-CO-C2H3（OH）-R <5> - 或-CO- NR <6> - [R <5> - ; [R <5> =亚烷基，亚芳基，亚芳基亚或亚芳基亚; [R <6> =氢，烷基或碳原子数为1〜10的芳基; [R <9>是氢，烷基，链烯基，芳基，烷芳基或芳基烷基; X =氢，卤素，羟基，烷氧基，酰氧基，烷基羰基，烷氧基羰基或NR “2，其中R”=氢，烷基或芳基; Y = -O - ， - S-或-NR <6> - ; Z = -O-或 - （CHR <6>）间 - ，其中m = 1或2; A = 1，2或3，其中b = 1α= 2或3; B = 1，2或3，其中a = 1对于b = 2或3; C = 1至6; X = 1，2或3; 一个+ X = 2，3或4