基本信息:
- 专利标题: PROCESS FOR PRODUCING N-ARYLHYDROXYLAMINES AND N-HETARYLHYDROXYLAMINES
- 专利标题(中):用于生产N-芳基和N- HETARYLHYDROXYLAMINEN
- 申请号:PCT/EP1996000170 申请日:1996-01-17
- 公开(公告)号:WO1996022967A1 公开(公告)日:1996-08-01
- 发明人: BASF AKTIENGESELLSCHAFT
- 申请人: BASF AKTIENGESELLSCHAFT , GÖTZ, Norbert , MÜLLER, Bernd , SAUTER, Hubert , GEBHARDT, Joachim , WAGNER, Oliver
- 专利权人: BASF AKTIENGESELLSCHAFT,GÖTZ, Norbert,MÜLLER, Bernd,SAUTER, Hubert,GEBHARDT, Joachim,WAGNER, Oliver
- 当前专利权人: BASF AKTIENGESELLSCHAFT,GÖTZ, Norbert,MÜLLER, Bernd,SAUTER, Hubert,GEBHARDT, Joachim,WAGNER, Oliver
- 优先权: DE195 19950128
- 主分类号: C07C239/10
- IPC分类号: C07C239/10
摘要:
A process for producing aromatic or heteroaromatic hydroxylamines of the general formula (I) in which R is an unsubstituted or substituted aryl radical or an unsubstituted or substituted hetaryl radical from the pyridine or quinoline group, by hydration of nitro compounds of the general formula (II) R -NO2 in which R has the above meaning, in the presence of a platinum catalyst on an active carbon carrier or in the presence of a sulphur or selenium-doped palladium catalyst on an active carbon carrier, process in which the reaction is conducted in the presence of a morpholine compound substituted at the nitrogen atom of the general formula (III) in which R are alkyl radicals with 1 to 5 carbon atoms and R to R are hydrogen atoms or alkyl radicals with 1 to 5 carbon atoms.
摘要(中):
用于制备通式(I)的芳族或杂芳族羟胺,<1>,其中R表示未取代或取代的芳基或未取代或由通式的硝基化合物的加氢取代选自吡啶或喹啉的杂芳基,(A过程II )R <1> -NO 2,<1>具有上文中给出的含义R,在铂催化剂的对活性炭载体或通过进行的在氮原子上取代的存在下进行反应的存在的掺杂有硫或硒钯催化剂在活化的碳载体的存在下 吗啉的通式(III)的化合物进行,其中R <3>至R <2>是具有1至5个碳原子的烷基基团,并且R <10>为氢原子或具有1至5个碳原子的烷基。
IPC结构图谱:
C | 化学;冶金 |
--C07 | 有机化学 |
----C07C | 无环或碳环化合物 |
------C07C239/00 | 含有氮—卤键的化合物;羟氨基化合物或它们的醚或酯 |
--------C07C239/02 | .含有氮—卤键的化合物 |
----------C07C239/10 | ..羟氨基的氮原子进一步连接在未取代烃基的碳原子上或被卤原子或硝基或亚硝基取代的烃基的碳原子上 |