
基本信息:
- 专利标题: CATALYSTS
- 专利标题(中):催化剂
- 申请号:US13518698 申请日:2010-12-21
- 公开(公告)号:US20130018156A1 公开(公告)日:2013-01-17
- 发明人: Luigi Resconi , Pascal Castro , Lauri Huhtanen
- 申请人: Luigi Resconi , Pascal Castro , Lauri Huhtanen
- 申请人地址: AT VIENNA
- 专利权人: BOREALIS AG
- 当前专利权人: BOREALIS AG
- 当前专利权人地址: AT VIENNA
- 优先权: EP09252863.7 20091222
- 国际申请: PCT/EP2010/070354 WO 20101221
- 主分类号: C08F4/6592
- IPC分类号: C08F4/6592 ; C08F110/06
摘要:
A solid particulate catalyst free from an external carrier comprising:(i) a complex of formula (I): whereinM is zirconium or hafnium;each X is a sigma ligand;L is a divalent bridge selected from —R′2C—, —R′2C—CR′2—, —R′2Si—, —R′2Si—SiR'2—, —R′2Ge—, wherein each R′ is independently a hydrogen atom, C1-C20-alkyl, tri(C1-C20-alkyl)silyl, C6-C20-aryl, C7-C20-arylalkyl or C7-C20-alkylaryl;each R1 independently is hydrogen or a linear or branched C1-C20 hydrocarbyl radical optionally containing one or more heteroatoms from groups 14-16 of the Periodic Table of the Elements;each R2 and R3 taken together form a 4-7 membered ring condensed to the benzene ring of the indenyl moiety, said ring optionally containing heteroatoms from groups 14-16, each atom forming said ring being optionally substituted with at least one R18 radical;each R18 is the same or different and may be a C1-C20 hydrocarbyl radical optionally containing one or more heteroatoms belonging to groups 14-16;each R4 is a hydrogen atom or a C1-6-hydrocarbyl radical optionally containing one or more heteroatoms belonging to groups 14-16;each W is independently a 5 or 6 membered aryl or heteroaryl ring wherein each atom of said ring is optionally substituted with an R5 group;each R5 is the same of different and is a C1-C20 hydrocarbyl radical optionally containing one or more heteroatoms belonging to groups 14-16; and optionally two adjacent R5 groups taken together can form a further mono or multicyclic ring condensed to W optionally substituted by one or two groups R5; and(ii) a cocatalyst comprising an organometallic compound of a Group 13 metal, preferably aluminoxane.
摘要(中):
不含外部载体的固体颗粒催化剂,其包含:(i)式(I)的络合物:其中M为锆或铪; 每个X是σ配体; L是选自-R'2C-,-R'2C-CR'2-,-R'2Si-,-R'2Si-SiR'2-,-R'2Ge-的二价桥,其中每个R' 独立地为氢原子,C 1 -C 20烷基,三(C 1 -C 20 - 烷基)甲硅烷基,C 6 -C 20 - 芳基,C 7 -C 20 - 芳基烷基或C 7 -C 20 - 烷基芳基; 每个R 1独立地是氢或任选地含有一个或多个元素周期表第14-16族的杂原子的直链或支链C 1 -C 20烃基; 每个R 2和R 3一起形成4-烯基部分的苯环稠合的4-7元环,所述环任选地含有14-16个杂原子,形成所述环的每个原子任选被至少一个R 18基团取代; 每个R 18相同或不同,并且可以是任选地含有一个或多个属于第14-16族的杂原子的C 1 -C 20烃基; 每个R 4是氢原子或任选地含有一个或多个属于第14-16族的杂原子的C 1-6烃基; 每个W独立地是5或6元芳基或杂芳基环,其中所述环的每个原子任选被R 5基团取代; 每个R 5是不同的,并且是任选地含有一个或多个属于第14-16族的杂原子的C 1 -C 20烃基; 并且任选地两个相邻的R5基团可以形成另外的一个或多个环,其被稠合至可任选地被一个或两个基团R 5取代的W; 和(ii)包含第13族金属的有机金属化合物,优选铝氧烷的助催化剂。
公开/授权文献:
- US09029284B2 Catalysts 公开/授权日:2015-05-12
IPC结构图谱:
C | 化学;冶金 |
--C08 | 有机高分子化合物;其制备或化学加工;以其为基料的组合物 |
----C08F | 仅用碳—碳不饱和键反应得到的高分子化合物 |
------C08F4/00 | 聚合催化剂 |
--------C08F4/42 | .金属;金属氢化物;金属有机化合物;及其作为催化剂母体的用途 |
----------C08F4/44 | ..选自轻金属、锌、镉、汞、铜、银、金、硼、镓、铟、铊、稀土元素或锕族元素 |
------------C08F4/60 | ...与高熔点金属、铁族金属、铂族金属、锰、锝、铼或它们的化合物在一起 |
--------------C08F4/607 | ....含有一种特殊的非金属或不含金属化合物的催化剂 |
----------------C08F4/627 | .....催化剂含有一种特殊的非金属或不含金属的化合物 |
------------------C08F4/647 | ......催化剂含有一种特殊的非金属或不含金属的化合物 |
--------------------C08F4/6592 | .......至少含1个环戊二烯环,稠合的或未稠合的,例如,茚基环或芴基环 |