基本信息:
- 专利标题： 산화 촉매계 및 이를 사용한 산화 방법
- 专利标题（英）：Oxidation Catalyst System and Method of Oxidation with the Same
- 专利标题（中）：氧化催化剂体系及其氧化方法
- 申请号：KR1019997009567 申请日：1999-02-10
- 公开(公告)号：KR1020010006477A 公开(公告)日：2001-01-26
- 发明人： 이시이,야스따까 , 나까노,다쯔야
- 申请人： 주식회사 다이셀
- 申请人地址： *-*, Ofuka-cho, Kita-ku, Osaka-shi, Osaka, Japan
- 专利权人： 주식회사 다이셀
- 当前专利权人： 주식회사 다이셀
- 当前专利权人地址： *-*, Ofuka-cho, Kita-ku, Osaka-shi, Osaka, Japan
- 代理人： 주성민; 위혜숙
- 优先权： JP98-54443 1998-02-18
- 国际申请： PCT/JP1999/000566 1999-02-10
- 国际公布： WO1999042211 1999-08-26
- 主分类号： B01J23/46
- IPC分类号： B01J23/46
摘要：
본발명의산화촉매계는, (A) 루테늄화합물과 (B) 디옥시벤젠류또는그의산화체로구성된다. 루테늄화합물 (A)에는, 디클로로트리스(트리페닐포스핀)루테늄(Ⅱ) 등의루테늄착체, Ru/C 등이포함된다. 디옥시벤젠류또는그의산화체 (B)에는히드로퀴논등이포함된다. 상기산화촉매계의존재하에분자상산소로알콜을산화시키면, 해당카르보닐화합물이높은수율로얻어진다. 제2급알콜에비하여제1급알콜이더 선택적으로산화된다.
摘要（英）：
Oxidation catalyst system of the present invention, consists of (A) the ruthenium compound and (B) dioxy benzenes or his body oxide. In the ruthenium compound (A), dichlorotris (triphenylphosphine) ruthenium complexes such as ruthenium (Ⅱ), and the like Ru / C. Deoxy benzenes or its oxidant (B) is hydroquinone, and the like. Oxidation of alcohols with molecular oxygen in the presence of the oxidation catalyst system, the corresponding carbonyl compound is obtained in a high yield. The first alcohol than the secondary alcohol is more selectively oxidized.
信息查询:
EspacenetIPC结构图谱:
| B | 作业；运输 |
| --B01 | 一般的物理或化学的方法或装置 |
| ----B01J | 化学或物理方法，例如，催化作用、胶体化学；其有关设备 |
| ------B01J23/00 | 不包含在B01J21/00组中的，包含金属或金属氧化物或氢氧化物的催化剂 |
| --------B01J23/16 | .砷、锑、铋、钒、铌、钽、钋、铬、钼、钨、锰、锝或铼的 |
| ----------B01J23/40 | ..铂系金属的 |
| ------------B01J23/46 | ...钌、铑、锇或铱 |