基本信息:
- 专利标题： 에틸렌성불포화화합물의카르보닐화방법
- 专利标题（英）：Carbonylation method of ethylenic unsaturated compound
- 专利标题（中）：乙烯不饱和化合物的碳化方法
- 申请号：KR1019980707537 申请日：1997-04-15
- 公开(公告)号：KR1020000004947A 公开(公告)日：2000-01-25
- 发明人： 드렌트아이트 , 드카스트로로레이로바레또로사마리아마뉴엘 , 길레스파이헤롤드몬크리에프 , 새비지폴데이빗 , 반헬덴아렌트퀸데르트 , 멕케나유진제라드
- 申请人： 쉘 인터내셔날 리써취 마트샤피지 비.브이.
- 申请人地址： 네델란드왕국 엔엘-**** 에이치알 더 헤이그 카렐 반 바일란드틀란 **
- 专利权人： 쉘 인터내셔날 리써취 마트샤피지 비.브이.
- 当前专利权人： 쉘 인터내셔날 리써취 마트샤피지 비.브이.
- 当前专利权人地址： 네델란드왕국 엔엘-**** 에이치알 더 헤이그 카렐 반 바일란드틀란 **
- 代理人： 특허법인코리아나
- 优先权： EP963026331 1996-04-16
- 国际申请： PCT/EP1997/001905 1997-04-15
- 国际公布： WO1997038964 1997-10-23
- 主分类号： C07C67/38
- IPC分类号： C07C67/38 ; C07C69/017 ; C07C69/24 ; C10M105/34
摘要：
PURPOSE: Many examples for converting olefine into ester, acid, anhydride and amide according to the class of co-reactant. are disclosed. Recently a modified method on the basis of the presence of amine was disclosed, which has greatly improved reaction rate. Also another method having better yield and large selectivity is disclosed, but has a problem that the reaction rate is too low. CONSTITUTION: The invention provides carbonylation reaction in which ethylenic unsaturated compound reacts with CO and co-reactant in the presence of catalyst system obtainable by bonding (1) supply source of 8 class metal cation, (2) phosphine, arsenic hydride or antimonial hydride acting as ligand, and (3) supply source of anion except halogen anion. The reaction is performed in the presence of substoichiometric amount of halogen anion or phenolic accelerant. Also the invention provides new alkyl phenol ester for use as a synthetic lubricant.
摘要（中）：
目的：根据共反应物类将烯烃转化为酯，酸，酐和酰胺的许多实例。 被披露。 最近公开了一种基于胺存在的改性方法，其反应速度大大提高。 还公开了另一种具有较好产率和大选择性的方法，但是反应速率太低的问题。 构成：本发明提供羰基化反应，其中烯属不饱和化合物与CO和共反应物在催化剂体系的存在下反应，催化剂体系可通过键合（1）8级金属阳离子的供应源，（2）膦，砷化氢或锑氢化物作用 作为配体，（3）阴离子供体源除卤素阴离子外。 反应在亚化学计量量的卤素阴离子或酚类促进剂的存在下进行。 本发明还提供了用作合成润滑剂的新型烷基酚酯。
公开/授权文献:
- KR100473473B1 에틸렌성불포화화합물의카르보닐화방법 公开/授权日：2005-05-16