基本信息:
- 专利标题: HETEROPOLY ACID/POLYOXOMETHALATE CATALYST
- 申请号:JP2000247492 申请日:2000-08-17
- 公开(公告)号:JP2001104793A 公开(公告)日:2001-04-17
- 发明人: ELLIS PAUL EDWARD , KARMAKAR SWATI , LINK RICHARD DAVID III , LYONS JAMES EDWARD , MCNEAL NNEKA NAMONO , VOLPE ANTHONY FRANK JR
- 申请人: ROHM & HAAS , SUNOCO INC
- 专利权人: ROHM & HAAS,SUNOCO INC
- 当前专利权人: ROHM & HAAS,SUNOCO INC
- 优先权: US14938399 1999-08-17
- 主分类号: B01J27/19
- IPC分类号: B01J27/19 ; B01J23/16 ; B01J27/188 ; B01J27/199 ; B01J31/06 ; B01J37/08 ; C07B61/00 ; C07C5/42 ; C07C11/02 ; C07C51/215 ; C07C57/05
摘要:
PROBLEM TO BE SOLVED: To provide an improved catalyst for various chemical processes, containing a heteropoly acid carried on a polyoxomethalate salt. SOLUTION: This heteropoly acid/oplyoxomethalate catalyst comprises a catalyst composition containing a heteropoly acid carried on a polyoxomethalate carrier, wherein the carrier of the polyoxomethalate is subjected to heat treatment at 385-600 deg.C. The heteropoly acid has a structure represented by the formula I, H(e'-bz')Gb-(Xk'Mm'-x'M1x'M2n'Oy')-e' (wherein G is an element selected from group 1-16 elements, or its oxygen; X is an element selected from group 3-16 elements; M is molybdenum, tungsten, or their combination; M1 is vanadium; M2 is a transition metal different from M and M1; z' is a charge of G; (b) is an integer of 0-12; k' is an integer of 1-5; m' is an integer of 5-20; x' is an integer of 0-6; n' is an integer of 0-3; y' is an integer of 18-62; and e' is a charge of polyoxomethalate anino). The polyoxomethalate carrier has a structure represented by the formula II, CaH(e-az)(XkMm-xM1xM2nOy)-e (wherein C is a cation selected from potassium, rubidium, cesium, magnetisum, calcium, strontium, barium, transistion metal, an actinide metal, a lanthanide metal, a metal oxyion, ammonium, tetraalkylammonium, pyridinium, quinolinium, a protonated aromatic amine, and a protonated aliphatic amine or a mixture thereof; (x) is an element selected from group 3-16 elements; M is molybdenum, tungsten, or their combination; M1 is vanadium; M2 is a transition metal different from M and M1; (z) is a charge of C; (k) is an integer of 1-5; (m) is an integer of 5-20; (n) is an integer of 0-3; x is an integer of 0-6; (y) is an integer of 18-62; and (e) is a charge of a olyoxomethalate anion). The polyoxomethalate carrier is, for example, Cs3PMo12O40, and the heteropoly acid is, for example, H3PMo12O40.
信息查询:
EspacenetIPC结构图谱:
B | 作业;运输 |
--B01 | 一般的物理或化学的方法或装置 |
----B01J | 化学或物理方法,例如,催化作用、胶体化学;其有关设备 |
------B01J27/00 | 包含卤素、硫、硒、碲、磷或氮的元素或化合物的催化剂;包含碳化合物的催化剂 |
--------B01J27/02 | .硫、硒或碲;它们的化合物 |
----------B01J27/186 | ..含砷、锑、铋、钒、铌、钽、钋、铬、钼、钨、锰、锝或铼 |
------------B01J27/188 | ...含铬、钼、钨或钋 |
--------------B01J27/19 | ....钼 |