![VERFAHREN ZUR OXIDATIVEN DEHYDRIERUNG VON N-BUTENEN ZU 1,3-BUTADIEN](/ep/2016/04/27/EP3010635A1/abs.jpg.150x150.jpg)
基本信息:
- 专利标题: VERFAHREN ZUR OXIDATIVEN DEHYDRIERUNG VON N-BUTENEN ZU 1,3-BUTADIEN
- 专利标题(英):Method for the oxidative dehydration of n-butenes into 1,3-butadien
- 申请号:EP14730527.0 申请日:2014-06-16
- 公开(公告)号:EP3010635A1 公开(公告)日:2016-04-27
- 发明人: OLBERT, Gerhard , AVERLANT, Gauthier Luc Maurice , GRÜNE, Philipp , JOSCH, Jan Pablo
- 申请人: BASF SE
- 申请人地址: Carl-Bosch-Strasse 38 67056 Ludwigshafen am Rhein DE
- 专利权人: BASF SE
- 当前专利权人: BASF SE
- 当前专利权人地址: Carl-Bosch-Strasse 38 67056 Ludwigshafen am Rhein DE
- 代理机构: Reitstötter Kinzebach
- 优先权: EP13172318 20130617
- 国际公布: WO2014202501 20141224
- 主分类号: B01J8/06
- IPC分类号: B01J8/06 ; C07C5/48 ; C07C11/167
摘要:
The invention relates to a method for producing 1,3 butadien by means of the oxidative dehydration of n-butenes on a heterogenous particulate multimetal oxide catalyst which contains molybdenum as the active compound and at least one other metal and which is filled into the contact tubes (KR) of two or more tube bundle reactors (R-I, R-II), wherein a heat transfer medium flows around the intermediate space between the contact tubes (KR) of the two or more tube bundle reactors (R-I, R-II). The method includes a production mode and a regeneration mode which are carried out in an alternating manner. In the production mode, an n-butene-containing feed flow is mixed with an oxygen-containing gas flow and conducted as a supply flow (1) over the heterogenous particulate multimetal oxide catalyst filled into the contact tubes (KR) of the two or more tube bundle reactors (R-I, R-II), and the heat transfer medium absorbs the released reaction heat, minus the heat quantity used to heat the supply flow (1) to the reaction temperature in the production mode, by means of an indirect heat exchange and completely or partly dispenses the reaction heat onto a secondary heat transfer medium (H
2 O
liq ) in an external cooler (SBK). In the regeneration mode, the heterogenous particulate multimetal oxide catalyst is regenerated by conducting an oxygen-containing gas mixture (3) over the catalyst and burning off the deposits accumulated on the heterogenous particulate multimetal oxide catalyst. The invention is characterized in that the two or more tube bundle reactors (R-I, R-II) have a single heat transfer medium circuit and as many of the two or more tube bundle reactors (R-I. R-II) as necessary are operated constantly in the production mode so that the released reaction heat, minus the heat quantity used to heat the supply flow (1) to the reaction temperature in the production mode, suffices to keep the temperature of the heat transfer medium in the intermediate spaces between the content tubes (KR) of all the tube bundle reactors (R-I, R-II) at a constant level with a variation range of maximally +/- 10 °C.
摘要(中):
2 O
liq ) in an external cooler (SBK). In the regeneration mode, the heterogenous particulate multimetal oxide catalyst is regenerated by conducting an oxygen-containing gas mixture (3) over the catalyst and burning off the deposits accumulated on the heterogenous particulate multimetal oxide catalyst. The invention is characterized in that the two or more tube bundle reactors (R-I, R-II) have a single heat transfer medium circuit and as many of the two or more tube bundle reactors (R-I. R-II) as necessary are operated constantly in the production mode so that the released reaction heat, minus the heat quantity used to heat the supply flow (1) to the reaction temperature in the production mode, suffices to keep the temperature of the heat transfer medium in the intermediate spaces between the content tubes (KR) of all the tube bundle reactors (R-I, R-II) at a constant level with a variation range of maximally +/- 10 °C.
本发明涉及一种通过正丁烯在含有钼作为活性化合物和至少一种其他金属的多相颗粒多金属氧化物催化剂上的氧化脱水来制备1,3-丁二烯的方法,该催化剂填充到接触管 (RI,R-II)的接触管(KR)之间的中间空间周围流动的两个或更多个管束反应器(RI,R-II) 。 该方法包括以交替方式执行的生产模式和再生模式。 在生产模式中,将含正丁烯的进料流与含氧气流混合,并作为供应流(1)在填充到两者的接触管(KR)中的异质颗粒多金属氧化物催化剂上传导,或者 更多的管束反应器(RI,R-II),并且传热介质吸收释放的反应热,减去用于将供给流(1)加热到生产模式中的反应温度的热量,通过间接 热交换并将反应热完全或部分分配到外部冷却器(SBK)中的第二传热介质(H 2 Oliq)上。 在再生模式中,通过在催化剂上引导含氧气体混合物(3)并烧掉聚集在异相颗粒多金属氧化物催化剂上的沉积物来再生异相颗粒多金属氧化物催化剂。 本发明的特征在于,两个或更多个管束反应器(RI,R-II)具有单个传热介质回路,并且根据需要使两个或更多个管束反应器(RI.R-II)中的许多管束反应器 在生产模式下,释放的反应热减去用于将供应流(1)加热到生产模式下的反应温度的热量,足以将传热介质的温度保持在中间空间中的含量 所有管束反应器(RI,R-II)的管(KR)处于恒定水平,变化范围最大为+/- 10°C。
IPC结构图谱:
B | 作业;运输 |
--B01 | 一般的物理或化学的方法或装置 |
----B01J | 化学或物理方法,例如,催化作用、胶体化学;其有关设备 |
------B01J8/00 | 在有流体和固体颗粒的情况下所进行的一般化学或物理的方法;这些方法所用的装置 |
--------B01J8/02 | .用静止颗粒,例如,在固定床内 |
----------B01J8/06 | ..在管式反应器内;固体颗粒分布在管内 |