
基本信息:
- 专利标题: A polyolefin preparation process with reduced tendency to reactor fouling
- 专利标题(中):Verfahren zur Polyolefinherstellung mit reduzierter Tendenz zur Reaktorfaulung
- 申请号:EP08168572.9 申请日:2008-11-07
- 公开(公告)号:EP2192133A1 公开(公告)日:2010-06-02
- 发明人: Hakala, Kimmo , Noopila, Tuomas , Tuominen, Olli , Leskinen, Pauli
- 申请人: Borealis AG
- 申请人地址: IZD Tower Wagramerstraße 17-19 1220 Vienna AT
- 专利权人: Borealis AG
- 当前专利权人: Borealis AG
- 当前专利权人地址: IZD Tower Wagramerstraße 17-19 1220 Vienna AT
- 代理机构: Maiwald Patentanwalts GmbH
- 主分类号: C08F10/00
- IPC分类号: C08F10/00 ; C08F2/00 ; C08F2/06 ; C08F2/14
摘要:
The present invention relates to a process for the preparation of a polyolefin, wherein ethylene and/or propylene are polymerised in a liquid or supercritical hydrocarbon reaction medium of a polymerisation reactor R1 in the presence of a solid catalyst composition and an antifouling composition, the solid catalyst composition comprising
(i) a transition metal compound of formula (I)
L m R n MX q (I)
wherein
M is a transition metal of anyone of the groups 3 to 10 of the periodic table (IUPAC),
each X is independently a monovalent anionic σ-ligand,
each L is independently an organic ligand which coordinates to the transition metal M,
R is a bridging group linking two organic ligands (L),
m is 1, 2 or 3,
n is 0, 1 or 2,
q is 1, 2 or 3,
m+q is equal to the valency of the transition metal M, and
(ii) a cocatalyst comprising a metal M' of Group 13 of the periodic table (IUPAC),
the solid catalyst composition having a porosity measured according to ASTM 4641 of less than 1.40 ml/g,
and
the antifouling composition comprising an organic compound which has at least 14 carbon atoms and comprises at least one polar functional group.
摘要(中):
(i) a transition metal compound of formula (I)
L m R n MX q (I)
wherein
M is a transition metal of anyone of the groups 3 to 10 of the periodic table (IUPAC),
each X is independently a monovalent anionic σ-ligand,
each L is independently an organic ligand which coordinates to the transition metal M,
R is a bridging group linking two organic ligands (L),
m is 1, 2 or 3,
n is 0, 1 or 2,
q is 1, 2 or 3,
m+q is equal to the valency of the transition metal M, and
(ii) a cocatalyst comprising a metal M' of Group 13 of the periodic table (IUPAC),
the solid catalyst composition having a porosity measured according to ASTM 4641 of less than 1.40 ml/g,
and
the antifouling composition comprising an organic compound which has at least 14 carbon atoms and comprises at least one polar functional group.
本发明涉及一种制备聚烯烃的方法,其中乙烯和/或丙烯在聚合反应器R1的液体或超临界烃反应介质中在固体催化剂组合物和防污组合物的存在下聚合,固体 催化剂组合物,其包含(i)式(I)的过渡金属化合物€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ(I) 其中M是元素周期表(IUPAC)中任何3至10族的过渡金属,每个X独立地是一价阴离子配体,每个L独立地是与过渡金属M相配的有机配体,R是 连接两个有机配体(L)的桥连基团,m为1,2或3,n为0,1或2,q为1,2或3,m + q等于过渡金属M的化合价, (ii)包含周期表第13族金属M'(IUPAC)的助催化剂,该固体催化剂组合物具有孔隙率 y根据ASTM 4641测量小于1.40ml / g,防污组合物包含具有至少14个碳原子并且包含至少一个极性官能团的有机化合物。
IPC结构图谱:
C | 化学;冶金 |
--C08 | 有机高分子化合物;其制备或化学加工;以其为基料的组合物 |
----C08F | 仅用碳—碳不饱和键反应得到的高分子化合物 |
------C08F10/00 | 只有1个碳—碳双键的不饱和脂族烃的均聚物或共聚物 |