发明公开
EP1904429A4 METHOD OF PRODUCING UNSATURATED ACID IN FIXED-BED CATALYTIC PARTIAL OXIDATION REACTOR WITH HIGH EFFICIENCY
有权
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基本信息:
- 专利标题: METHOD OF PRODUCING UNSATURATED ACID IN FIXED-BED CATALYTIC PARTIAL OXIDATION REACTOR WITH HIGH EFFICIENCY
- 专利标题(中):用于生产不饱和酸在催化FESTBETTEILOXIDATIONSREAKTOR高效率
- 申请号:EP06783285 申请日:2006-07-07
- 公开(公告)号:EP1904429A4 公开(公告)日:2009-02-18
- 发明人: WOO BOO GON , HA KYOUNG SU , CHOI SEOK HWAN , KANG SEONG PIL , KO JUN SEOK , KIM YOUNG BAE
- 申请人: LG CHEMICAL LTD
- 专利权人: LG CHEMICAL LTD
- 当前专利权人: LG CHEMICAL LTD
- 优先权: KR20050061797 2005-07-08
- 主分类号: C07C45/27
- IPC分类号: C07C45/27
摘要:
Disclosed is a process for producing unsaturated aldehydes and/or unsaturated acids from olefins or alkanes in a fixed bed shell-and-tube heat exchanger-type reactor by catalytic vapor phase oxidation. A heat exchanger-type reactor for use in such a process is also disclosed. In the process, at least one of the first-step reaction zone and the second-step reaction zone is divided into two or more shell spaces by at least one partition; each of the divided shell spaces is independently heat-controlled; a heat transfer medium in the first shell space of the first-step reaction zone or the first shell space of the second-step reaction zone has a temperature ranging from the lowest active temperature of a catalyst layer packed in a reaction tube corresponding to the first shell space of the first-step reaction zone or the first shell space of the second-step reaction zone to [the lowest active temperature + 20 °C], when referring to the two or more shell spaces corresponding to the first-step reaction zone sequentially as the first shell space of the first-step reaction zone, the second shell space of the first-step reaction zone, ..., the nth shell space of the first-step reaction zone, and the two or more shell spaces corresponding to the second-step reaction zone sequentially as the first shell space of the second-step reaction zone, the second shell space of the second-step reaction zone, ... , the nth shell space of the second-step reaction zone; and the first shell space of the first-step reaction zone or the first shell space of the second-step reaction zone is controlled in such a manner that the first shell space provides a reactant conversion contribution per length as defined in Equation 1 or 2 of 1.2∼2.5.