基本信息:
- 专利标题： Process for producing an aliphatic isocyanate
- 专利标题（中）：伊斯法罕zur Herstellung eines aliphatischen异氰酸酯。
- 申请号：EP85104993.2 申请日：1985-04-24
- 公开(公告)号：EP0161550A1 公开(公告)日：1985-11-21
- 发明人： Fukuoka, Shinsuke 2-904, Asahi-Kasei-Ohtaka-Apt , Watanabe, Tomonari 2-407, Asahi-Kasei-Ohtaka-Apt
- 申请人： Asahi Kasei Kogyo Kabushiki Kaisha
- 申请人地址： 2-6, Dojimahama 1-chome Kita-ku Osaka-shi Osaka 530 JP
- 专利权人： Asahi Kasei Kogyo Kabushiki Kaisha
- 当前专利权人： Asahi Kasei Kogyo Kabushiki Kaisha
- 当前专利权人地址： 2-6, Dojimahama 1-chome Kita-ku Osaka-shi Osaka 530 JP
- 代理机构： Strehl Schübel-Hopf Groening & Partner
- 优先权： JP82858/84 19840426; JP224118/84 19841026
- 主分类号： C07C119/042
- IPC分类号： C07C119/042 ; C07C118/00
摘要：
A process for producing an aliphatic isocyanate from an aliphatic primary amine comprising a carbonylation step in which an aliphatic primary amine is allowed to react with carbon monoxide at a temperature of about 100-250°C in the presence of an aromatic hydroxyl compound having a pKa value of not more than about 11, molecular oxigen and a catalyst system comprising at least one member selected from palladium and rhodium metals and components thereof and at least one member selected from iodine and bromine and compounds thereof and a combined separation and recovery step comprising a pyrolysis-distillation reaction in which the mixture of carbonylated products is heated to a temperature of from about 100 to 300°C.
摘要（中）：
一种由脂肪族伯胺生产脂肪族异氰酸酯的方法，包括羰基化步骤，其中在约100-250℃的温度下，使脂族伯胺与一氧化碳在芳族羟基化合物存在下反应，所述芳族羟基化合物具有 pKa值不大于约11，分子氧和催化剂体系包含选自钯和铑金属及其组分的至少一种和选自碘和溴的至少一种及其化合物，以及组合的分离和回收步骤 包括热解 - 蒸馏反应，其中将羰基化产物的混合物加热至约100至300℃的温度。
公开/授权文献:
- EP0161550B1 Process for producing an aliphatic isocyanate 公开/授权日：1988-01-20