基本信息:
- 专利标题：
- 申请号：DE69734958 申请日：1997-10-02
- 公开(公告)号：DE69734958D1 公开(公告)日：2006-02-02
- 发明人： VALLEE ALAIN , ARMAND MICHEL , OLLIVRIN XAVIER , MICHOT CHRISTOPHE
- 申请人： CENTRE NAT RECH SCIENT , HYDRO QUEBEC
- 专利权人： CENTRE NAT RECH SCIENT,HYDRO QUEBEC
- 当前专利权人： CENTRE NAT RECH SCIENT,HYDRO QUEBEC
- 优先权： CA2187046 1996-10-03
- 主分类号： C07C19/07
- IPC分类号： C07C19/07 ; C07C25/18 ; C07C245/14 ; C07C307/02 ; C07C311/48 ; C07C317/02 ; C07C381/12 ; C07F17/00 ; C08F2/46 ; C08F4/42 ; C08F12/02 ; C08F112/14 ; C08F220/12 ; C08F230/04 ; C08G59/68 ; C08G75/02 ; C08G77/08 ; C08G77/24 ; C08G79/00 ; C09K3/00 ; G03F7/00 ; G03F7/004
摘要：
Ionic compound is claimed which contains at least one A X group in which A is cation selected from biaryliodonium, arylsulphonium, arylacylsulphonium, diazonium, and organometallic cations containing transition metal complexed by at least one 4-12C unsaturated cyclic compound; said cationic group eventually becoming part of polymer chain; and X is imiduric anionÄFSO2NSO2R'fÜ , ÄRfCH2OSO2NSO2R'fÜ , Ä(Rf)2CHOSO2NSO2R'fÜ , or methyluric anion ÄFSO2C(Q)SO2R'fÜ , ÄRfCH2OSO2C(Q)SO2R'fÜ , or Ä(Rf)2CHOSO2C(Q)SO2R'fÜ ; in which Q = H, Cl, F-, Br, CN, or 1-30C alkyl, or 6-30C aryl, alkylaryl, or arylalkyl, or groups selected from R"f, R"fSO2, R"fCH2OSO2, (R"f)2CHOSO2; Rf, R'f, R"f are selected, when X is methyluric, from fluorine, 1-30C perhaloalkyl, 2-30C (perhaloalkyl)alkoxy, 3-30C perhalogenocycloaliphatic, possibly containing heteroatoms and/or perhaloalkyl chain, and 6-30C perhalogenated aryl; or better, Rf, R'f form divalent rad ical selected from 2-8C perfluoroalkene; or better still, R'f, R"f , or Rf, R"f form said divalent radical. Also claimed are: (1) preparation of the compound; (2) method for polymerisation or crosslinking using the compound as photoinitiator; and (3) modification of solubility properties of a polymer, containing acid-sensitive groups, which uses the compound.
公开/授权文献:
- DE69734958T2 公开/授权日：2006-08-10