
基本信息:
- 专利标题: 原子转移自由基聚合制备缓凝型超塑化剂的方法
- 专利标题(英):Method for preparing delayed coagulation type super plasticizer through atom transfer radical polymerization
- 申请号:CN201910162754.X 申请日:2019-03-05
- 公开(公告)号:CN109942754A 公开(公告)日:2019-06-28
- 发明人: 刘晓 , 管佳男 , 崔素萍 , 王子明 , 许谦 , 白夏冰 , 钱珊珊
- 申请人: 北京工业大学
- 申请人地址: 北京市朝阳区平乐园100号
- 专利权人: 北京工业大学
- 当前专利权人: 山东天恒万合新型建材有限公司
- 当前专利权人地址: 256600 山东省滨州市邹平市台子镇宋坊村村委东1000米
- 代理机构: 北京思海天达知识产权代理有限公司
- 代理人: 刘萍
- 主分类号: C08F261/02
- IPC分类号: C08F261/02 ; C08F261/04 ; C08F220/06 ; C08F220/56 ; C08F222/02 ; C08F118/08 ; C08F118/10 ; C08F8/12 ; C04B24/26 ; C04B103/32
The invention relates to a method for preparing a delayed coagulation type super plasticizer through atom transfer radical polymerization. The method comprises the steps of with a delayed coagulationtype monomer and a carboxylic acid small monomer as main reaction raw materials, sequentially carrying out atom transfer radical polymerization (ATRP), alcoholysis and copolymerization so as to prepare the delayed coagulation type super plasticizer, namely that carrying out atom transfer radical polymerization (ATRP) on the delayed coagulation type monomer as a reactant under the system formed byan unsaturated initiator, transition metal halide and a ligand so as to obtain an unsaturated macromonomer, carrying out alcoholysis so as to obtain a delayed coagulation type macromonomer, and copolymerizing with the carboxylic acid small monomer, so as to obtain the delayed coagulation type super plasticizer. According to the method, a functional side chain consisting of delayed coagulation typestructural monomers is innovatively designed and synthesized by virtue of a controllable polymerization technical measure, a traditional polymer side chain structure is replaced, the super plasticizer presents excellent capacities of dispersing element purified slurry, and the coagulation time of the element purified slurry can be remarkably delayed, so that the later-period strength of concreteis improved, and multiple effects of high water reduction, slump resistance and delayed coagulation are achieved.
公开/授权文献:
- CN109942754B 原子转移自由基聚合制备缓凝型超塑化剂的方法 公开/授权日:2021-06-25
IPC结构图谱:
C | 化学;冶金 |
--C08 | 有机高分子化合物;其制备或化学加工;以其为基料的组合物 |
----C08F | 仅用碳—碳不饱和键反应得到的高分子化合物 |
------C08F261/00 | 由单体接到C08F16/00组所规定的含氧单体的聚合物上聚合而得到的高分子化合物 |
--------C08F261/02 | .接到不饱和醇的聚合物上 |