![从钨酸钠浸出液中回收碳酸钠的方法](/CN/2019/1/45/images/201910229194.jpg)
基本信息:
- 专利标题: 从钨酸钠浸出液中回收碳酸钠的方法
- 专利标题(英):Method for recovering sodium carbonate from sodium tungstate leaching solution
- 申请号:CN201910229194.5 申请日:2019-03-25
- 公开(公告)号:CN109824064A 公开(公告)日:2019-05-31
- 发明人: 霍广生 , 蒲海鹏 , 易新涛 , 刘辉 , 郭磊 , 马顺 , 曾璐琦 , 朱和平
- 申请人: 中南大学
- 申请人地址: 湖南省长沙市岳麓区麓山南路932号
- 专利权人: 中南大学
- 当前专利权人: 中南大学
- 当前专利权人地址: 湖南省长沙市岳麓区麓山南路932号
- 代理机构: 长沙永星专利商标事务所
- 代理人: 何方
- 主分类号: C01D7/24
- IPC分类号: C01D7/24 ; C01G41/00
The invention discloses a method for recovering sodium carbonate from a sodium tungstate leaching solution, andbelongs to the field of resource recycling.Aiming at a feature that a concentration of WO3 in the sodium tungstate leaching solution is lower generally, the method comprises the following steps of: firstly, concentrating the sodium tungstate leaching solution, improving an initial concentration of Na2CO3 in the solution as much as possible to improve a crystallization rate of the sodium carbonate in a freezing crystallization process, and simultaneously ensuring a proper initial concentration of WO3 to prevent the sodium tungstate from crystallizing together with the sodium carbonate.By the adoption of the method for recovering the sodium carbonate from the sodium tungstate leaching solution,a direct freezing crystallization method is combined with an NaHCO3 crystallization method, most of sodium carbonate crystal are recovered by the direct freezing crystallization method, thereby reducing the consumption of subsequently-injected CO2 and neutralization time of ventilation, meanwhile, further improving a total recovery rate of the sodium carbonate through the NaHCO3 crystallization method, and covering the shortage of low recovery rate of the direct freezing crystallization method; and aiming at the feature that temperature-lowering is slow in a later period in a cooling and temperature-lowering process, crushed ice blocks are directly added to dissolve and rapidly lower the temperature, thereby greatly improving the productioneffectiveness.
公开/授权文献:
- CN109824064B 从钨酸钠浸出液中回收碳酸钠的方法 公开/授权日:2020-02-07