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基本信息:
- 专利标题: 一种并流型滴流固定床中线性烯烃与过氧化氢的环氧化催化方法
- 专利标题(英):Epoxidation catalyzing method of linear alpha olefins and hydrogen peroxide in parallel-flow-type dripping fixed bed
- 申请号:CN201811366291.0 申请日:2018-11-16
- 公开(公告)号:CN109678817A 公开(公告)日:2019-04-26
- 发明人: 夏清华 , 鲁新环 , 周丹
- 申请人: 湖北大学
- 申请人地址: 湖北省武汉市武昌区友谊大道368号
- 专利权人: 湖北大学
- 当前专利权人: 湖北大学
- 当前专利权人地址: 湖北省武汉市武昌区友谊大道368号
- 代理机构: 武汉开元知识产权代理有限公司
- 代理人: 俞鸿; 张敏
- 主分类号: C07D301/12
- IPC分类号: C07D301/12 ; C07D303/08 ; C07D303/04 ; C07D303/28 ; C07D303/14 ; B01J29/70 ; B01J35/10
The invention discloses an epoxidation catalyzing method of linear alpha olefins and hydrogen peroxide in a parallel-flow-type dripping fixed bed. The epoxidation catalyzing method comprises the following steps: at the temperature of 20-70 DEG C, mixed liquid of the linear alpha olefins, the hydrogen peroxide and a solvent is introduced from the upper end of the parallel-flow-type dripping fixed bed in a parallel-flow mode; the parallel-flow-type dripping fixed bed is filled with an HBMZ molecular sieve catalyst; the flow-parallelled reaction mixed liquid makes contact with the HBMZ molecularsieve catalyst from top to bottom; a reaction product flows out from the lower end of the parallel-flow-type dripping fixed bed; and then after the reaction product is subjected to low-temperature condensation through a condensation pipe and separated through a gas-liquid separator in sequence, a product, namely epoxide is obtained. According to the epoxidation catalyzing method, the alpha olefins, the hydrogen peroxide and the catalyst can make full contact, the catalytic activity is good, the utilization rate of the hydrogen peroxide is high, selectivity of the epoxy product is good, a process is simple, poisons and harm are avoided, the life of the catalyst is long, the online time is long, selectivity of the product is high, and industrial production is easy.
公开/授权文献:
- CN109678817B 一种并流型滴流固定床中线性烯烃与过氧化氢的环氧化催化方法 公开/授权日:2023-02-03
IPC结构图谱:
C | 化学;冶金 |
--C07 | 有机化学 |
----C07D | 杂环化合物 |
------C07D301/00 | 环氧乙烷的制备 |
--------C07D301/02 | .环氧乙烷环的合成 |
----------C07D301/03 | ..通过不饱和化合物的氧化,或通过不饱和化合物与饱和化合物的混合物的氧化 |
------------C07D301/12 | ...用过氧化氢或无机过氧化物或过酸 |