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基本信息:
- 专利标题: 一种联产甲基苯甲酸、甲基苯甲腈和苯二甲腈方法
- 专利标题(英):Method for coproducing methylbenzoic acid, methyl benzonitrie and phthalonitrile
- 申请号:CN201810819052.X 申请日:2018-07-24
- 公开(公告)号:CN108863757A 公开(公告)日:2018-11-23
- 发明人: 王勤波 , 熊振华 , 宗匡 , 曹金辉 , 曾鹏
- 申请人: 江西科苑生物药业有限公司
- 申请人地址: 江西省九江市彭泽县矶山工业园
- 专利权人: 江西科苑生物药业有限公司
- 当前专利权人: 江西科苑生物股份有限公司
- 当前专利权人地址: 江西省九江市彭泽县矶山工业园
- 代理机构: 宁波奥圣专利代理事务所
- 代理人: 程晓明
- 优先权: 2017113275133 20171213 CN
- 主分类号: C07C51/265
- IPC分类号: C07C51/265 ; C07C51/44 ; C07C63/04 ; C07C253/22 ; C07C253/34 ; C07C255/50 ; C07C255/51
The invention discloses a method for coproducing methylbenzoic acid, methyl benzonitrie and phthalonitrile. The method comprises the following steps: (1) continuously introducing xylol, a catalyst andoxygen-containing gas into an oxidation reactor and reacting to obtain an oxidation reaction solution; (2) conveying the oxidation reaction solution into a primary evaporation tower and carrying outrectification separation; when the content of methylbenzyl alcohol in a tower kettle solution of the primary evaporation tower reaches 0.01 to 0.15 weight percent, stopping rectification, so as to obtain a low-boiling-point component and the tower kettle solution of the primary evaporation tower; (3) conveying the tower kettle solution of the primary evaporation tower into a rectification tower and carrying out rectification; when the content of the methylbenzoic acid in a tower kettle solution of the rectification tower reaches 30 to 90 weight percent, stopping rectification, so as to obtaina methylbenzoic acid product and the tower kettle solution of the rectification tower; (4) mixing the tower kettle solution of the rectification tower and ammonia to obtain a nitrile-containing reaction solution; (5) carrying out rectification separation on the nitrile-containing reaction solution to obtain methyl benzonitrie and phthalonitrile products. The method disclosed by the invention has the advantages of simple technology, few equipment investment, greenness and environment protection and good comprehensive economic benefits.
公开/授权文献:
- CN108863757B 一种联产甲基苯甲酸、甲基苯甲腈和苯二甲腈方法 公开/授权日:2021-05-11
IPC结构图谱:
C | 化学;冶金 |
--C07 | 有机化学 |
----C07C | 无环或碳环化合物 |
------C07C51/00 | 羧酸或它们的盐、卤化物或酐的制备 |
--------C07C51/16 | .用氧化 |
----------C07C51/21 | ..用分子氧 |
------------C07C51/255 | ...含六元芳环无环裂开的化合物的 |
--------------C07C51/265 | ....有烷基侧链被氧化成羧基 |