基本信息:
- 专利标题： 一种Zr(IV)化合物的制备方法及在还原二氧化碳为甲醇中的应用
- 专利标题（英）：Preparation method of Zr(IV) compound as well as application of Zr(IV) compound to reducing carbon dioxide into methanol
- 申请号：CN201711471627.5 申请日：2017-12-29
- 公开(公告)号：CN108129506A 公开(公告)日：2018-06-08
- 发明人： 马建功 , 陈景获 , 程鹏
- 申请人： 南开大学
- 申请人地址： 天津市南开区卫津路94号
- 专利权人： 南开大学
- 当前专利权人： 南开大学
- 当前专利权人地址： 天津市南开区卫津路94号
- 代理机构： 天津耀达律师事务所
- 代理人： 廖晓荣
- 主分类号： C07F7/00
- IPC分类号： C07F7/00 ; C07C29/159 ; C07C31/04
A Zr(IV) compound and application thereof to reducing carbon dioxide into methanol comprise the following steps: 1) in a glove box, weighing the Zr(IV) compound Cl3THF2ZrBH4, putting the Zr(IV) compound Cl3THF2ZrBH4 into a Schlenk bottle and adding tetrahydrofuran; 2) taking out the Schlenk bottle from the glove box, connecting with a vacuum line, degassing, connecting the Schlenk bottle with a balloon full of carbon dioxide and reacting at room temperature for 12 hours; and 3) after the reaction, performing hydrolysis to obtain methanol, wherein the yield is 72.5 percent. The preparation method of the Zr(IV) compound Cl3THF2ZrBH4 is simple, low in raw material cost and easy in industrialized amplified production. The Zr(IV) compound can reduce the carbon dioxide into methanol under the conditions of normal temperature and normal pressure, and NaCl and boric acid which are generated in the reaction process can be continuously recycled, so industrial circulation can be realized and theaim of sustainable production can be fulfilled.
公开/授权文献:
- CN108129506B 一种Zr(IV)化合物的制备方法及在还原二氧化碳为甲醇中的应用 公开/授权日：2020-05-26
IPC结构图谱:
| C | 化学；冶金 |
| --C07 | 有机化学 |
| ----C07F | 含除碳、氢、卤素、氧、氮、硫、硒或碲以外的其他元素的无环，碳环或杂环化合物 |
| ------C07F7/00 | 含周期表第Ⅳ族元素的化合物 |