
基本信息:
- 专利标题: 无水氯化镨的制备方法
- 专利标题(英):Preparation method for anhydrous praseodymium chloride
- 申请号:CN201710818303.8 申请日:2017-09-12
- 公开(公告)号:CN107827139A 公开(公告)日:2018-03-23
- 发明人: 韩继龙 , 孙庆国 , 都永生 , 火焱
- 申请人: 中国科学院青海盐湖研究所
- 申请人地址: 青海省西宁市新宁路18号
- 专利权人: 中国科学院青海盐湖研究所
- 当前专利权人: 中国科学院青海盐湖研究所
- 当前专利权人地址: 青海省西宁市新宁路18号
- 代理机构: 深圳市铭粤知识产权代理有限公司
- 代理人: 孙伟峰
- 主分类号: C01F17/00
- IPC分类号: C01F17/00
The invention discloses a preparation method for anhydrous praseodymium chloride. The method comprises the following steps: step 1, performing first-stage fluidization dehydration on praseodymium chloride heptahydrate under the temperature of 60 DEG C-100 DEG C to obtain a crude product of praseodymium chloride trihydrate; step 2, performing second-stage fluidization dehydration on the crude product of the praseodymium chloride trihydrate under the temperature of 120 DEG C-130 DEG C to obtain a crude product of praseodymium chloride monohydrate; and step 3, performing third-stage fluidizationdehydration on the crude product of the praseodymium chloride monohydrate under the temperature of 140 DEG C-160 DEG C to obtain the anhydrous praseodymium chloride, wherein the third-stage fluidization dehydration is carried out in a hydrogen chloride gas atmosphere. According to the preparation method for the anhydrous praseodymium chloride provided by the invention, the praseodymium chloride heptahydrate is subjected to staged fluidization dehydration, and the hydrogen chloride protection gas atmosphere is provided, so that hydrolysis in the process of dehydration of the intermediate product praseodymium chloride monohydrate to the anhydrous praseodymium chloride is effectively inhibited, and the product purity is greatly improved; and the preparation method for the anhydrous praseodymium chloride has the advantages of a low dehydration temperature, low preparation costs and good dehydration effects.
IPC结构图谱:
C | 化学;冶金 |
--C01 | 无机化学 |
----C01F | 金属铍、镁、铝、钙、锶、钡、镭、钍的化合物,或稀土金属的化合物 |
------C01F17/00 | 稀土金属,即钪、钇、镧或镧系的化合物 |