
基本信息:
- 专利标题: 一种过渡金属改性硅镁沸石催化剂的制备方法
- 专利标题(英):Preparation method of transition metal modified silicon-magnesium zeolite catalyst
- 申请号:CN201710727281.4 申请日:2017-08-23
- 公开(公告)号:CN107497481A 公开(公告)日:2017-12-22
- 发明人: 牛建瑞 , 钱恒力 , 王曼 , 段二红 , 刘洁 , 刘浩彬
- 申请人: 河北科技大学
- 申请人地址: 河北省石家庄市裕华东路70号
- 专利权人: 河北科技大学
- 当前专利权人: 河北科技大学
- 当前专利权人地址: 河北省石家庄市裕华东路70号
- 代理机构: 石家庄新世纪专利商标事务所有限公司
- 代理人: 赵婧; 李志民
- 主分类号: B01J29/78
- IPC分类号: B01J29/78 ; B01D53/86 ; B01D53/72
The invention relates to a preparation method of a transition metal modified silicon-magnesium zeolite catalyst. The preparation method comprises steps as follows: a, magnesium sulfate is added to deionized water, concentrated sulfuric acid is added, and a solution A is obtained; b, a silicon source is added to the deionized water, and a solution B is obtained; c, the solution A is slowly added to the solution B, meanwhile, a template agent is added, and a solution C is obtained; d, the solution C is stirred for 0.5 h at high speed, and obtained gel is put in a hydrothermal crystallization kettle for crystallization; e, a solution obtained after crystallization in the step d is subjected to suction filtration, a mother solution is removed, a product is dried in a drying oven at the temperature of 100 DEG C for 24 h, and raw silicon-magnesium zeolite powder is obtained; f, the raw silicon-magnesium zeolite powder is added to a metallic nitrate solution and stirred for 2 h, a co-precipitation agent is dropwise added, pH is regulated to 10, a mixture is stirred and dried in the shade, and a catalyst precursor is obtained; g, the catalyst precursor is roasted at the temperature of 500-600 DEG C. The silicon-magnesium zeolite catalyst prepared with the method has the advantages of high catalytic activity and good stability.
公开/授权文献:
- CN107497481B 一种过渡金属改性硅镁沸石催化剂的制备方法 公开/授权日:2019-12-13
IPC结构图谱:
B | 作业;运输 |
--B01 | 一般的物理或化学的方法或装置 |
----B01J | 化学或物理方法,例如,催化作用、胶体化学;其有关设备 |
------B01J29/00 | 包含分子筛的催化剂 |
--------B01J29/03 | .不具有碱交换特性 |
----------B01J29/06 | ..硅铝酸盐 |
------------B01J29/08 | ...八面沸石型的,例如,X型或Y型的 |
--------------B01J29/78 | ....含砷、锑、铋、钒、铌、钽、钋、铬、钼、钨、锰、锝或铼 |