![一种脂肪族聚碳酸酯共聚酯及其制备方法](/CN/2017/1/135/images/201710676364.jpg)
基本信息:
- 专利标题: 一种脂肪族聚碳酸酯共聚酯及其制备方法
- 专利标题(英):Aliphatic polycarbonate copolyester and preparation method thereof
- 申请号:CN201710676364.5 申请日:2017-08-09
- 公开(公告)号:CN107474229A 公开(公告)日:2017-12-15
- 发明人: 李会玲 , 王红丹 , 王兴祥 , 彭丽君
- 申请人: 常州化学研究所
- 申请人地址: 江苏省常州市常武中路801号
- 专利权人: 常州化学研究所
- 当前专利权人: 常州化学研究所
- 当前专利权人地址: 江苏省常州市常武中路801号
- 代理机构: 北京中政联科专利代理事务所
- 代理人: 曹军
- 主分类号: C08G63/64
- IPC分类号: C08G63/64 ; C08G63/78
The invention discloses a high molecular weight aliphatic polycarbonate copolyester and a preparation method thereof, and relates to a multi-step ester exchange reaction and a high-temperature high-vacuum polycondensation reaction of aliphatic polyhydric alcohols, 2,5-furandicarboxylic acid and carbonic acid aryl esters. The ester exchange reaction and the polycondensation reaction are implemented continuously, so that the ester exchange reaction time is shortened, the equipment utilization rate is improved, no extra catalyst is needed before polycondensation, and thus the experiment steps are simplified. According to the copolyester disclosed by the invention, furandicarboxylic acid polyester structure units or chain segments are introduced into aliphatic polycarbonate main chains, so that the copolyester has the biodegradation of the aliphatic polycarbonate and excellent thermodynamic and processing proprieties of the furandicarboxylic acid polyester simultaneously, defects that the aliphatic polycarbonate is low in glass-transition temperature, low in melting temperature, low in crystallization temperature and the like are overcome, and requirements of different industries are met.
公开/授权文献:
- CN107474229B 一种脂肪族聚碳酸酯共聚酯及其制备方法 公开/授权日:2020-05-01
IPC结构图谱:
C | 化学;冶金 |
--C08 | 有机高分子化合物;其制备或化学加工;以其为基料的组合物 |
----C08G | 用碳—碳不饱和键以外的反应得到的高分子化合物 |
------C08G63/00 | 由在高分子主链上形成羧酸酯键的反应制得的高分子化合物 |
--------C08G63/64 | .含有羧酸酯基与碳酸酯基两者的聚酯 |