![一种利用煤矸石制备磁性P型分子筛的方法](/CN/2017/1/118/images/201710591881.jpg)
基本信息:
- 专利标题: 一种利用煤矸石制备磁性P型分子筛的方法
- 专利标题(英):Method for preparing magnetic P-type molecular sieve by using coal gangue
- 申请号:CN201710591881.2 申请日:2017-07-19
- 公开(公告)号:CN107285341A 公开(公告)日:2017-10-24
- 发明人: 杨建利
- 申请人: 西安科技大学
- 申请人地址: 陕西省西安市雁塔中路58号
- 专利权人: 西安科技大学
- 当前专利权人: 西安科技大学
- 当前专利权人地址: 陕西省西安市雁塔中路58号
- 代理机构: 西安创知专利事务所
- 代理人: 谭文琰
- 主分类号: C01B39/50
- IPC分类号: C01B39/50 ; B01J20/18
The invention discloses a method for preparing a magnetic P-type molecular sieve by using coal gangue. The method comprises: 1, grinding coal gangue, and carrying out high temperature calcining activating on the grinded coal gangue by using sodium carbonate; 2, oxidizing at a low temperature, adding hydrochloric acid, soaking, and filtering; 3, preparing an iron-doped molecular sieve from the filtration residue and the filtrate obtained after the filtration; and 4, placing the iron-doped molecular sieve in a porcelain boat, placing the porcelain boat in a tubular furnace, introducing nitrogen into the tube furnace, introducing hydrogen after the air in the tubular furnace is completely discharged, heating to a temperature of 650-700 DEG C, continuously carrying out a reduction reaction for 2-3 h, introducing nitrogen after completing the reaction, and cooling to a room temperature to obtain the magnetic P-type molecular sieve. According to the present invention, the coal gangue is used as the raw material, the Fe<3+> dissolution is performed with hydrochloric acid and is complexed by adding oxalic acid, and finally high temperature reduction is performed to prepare the magnetic P-type molecular sieve; the magnetic P-type molecular sieve has characteristics of high specific surface area and strong adsorption performance; and the magnetic P-type molecular sieve is easy to separate and recover through the external magnetic field, and the problem of high cost of the molecular sieve synthesis is solved.
公开/授权文献:
- CN107285341B 一种利用煤矸石制备磁性P型分子筛的方法 公开/授权日:2019-12-13
IPC结构图谱:
C | 化学;冶金 |
--C01 | 无机化学 |
----C01B | 非金属元素;其化合物 |
------C01B39/00 | 具有分子筛和碱交换特性的化合物,如结晶沸石;其制备;后处理,如离子交换或脱铝作用 |
--------C01B39/50 | .在晶格骨架中夹杂无机碱或盐通道的沸石,如钠沸石、钙霞石、黝方石、蓝方石 |