
基本信息:
- 专利标题: 废钒催化剂综合回收利用方法
- 专利标题(英):Comprehensive recovery and utilization method for waste vanadium catalyst
- 申请号:CN201710420164.3 申请日:2017-06-06
- 公开(公告)号:CN107177737A 公开(公告)日:2017-09-19
- 发明人: 郝喜才 , 娄童芳 , 姬红 , 占桂荣 , 曹明 , 师兆忠
- 申请人: 开封大学
- 申请人地址: 河南省开封市龙亭区东京大道
- 专利权人: 开封大学
- 当前专利权人: 开封大学
- 当前专利权人地址: 河南省开封市龙亭区东京大道
- 代理机构: 河南科技通律师事务所
- 代理人: 张晓辉; 樊羿
- 主分类号: C22B7/00
- IPC分类号: C22B7/00 ; C22B26/10 ; C22B34/22 ; C22B3/38 ; C01B33/32
The invention discloses a comprehensive recovery and utilization method for a waste vanadium catalyst. The method comprises the steps that water leaching and reductive acid leaching are sequentially conducted on the waste vanadium catalyst; silicon is separated and recycled by being prepared into sodium silicate through alkaline leaching in a residue leaching mode; single-stage extraction is conducted on leachate through saponification P204, vanadium and potassium are extracted and separated through vanadium extraction technologies of tail liquid concentration and separate re-extraction, potassium is separated by preparing potassium sulphate from raffinate through evaporation and concentration, and vanadium is recycled by preparing vanadium pentoxide from an extraction phase through the processes of back extraction, vanadium precipitation, calcination and the like. Through the extremely high selection characteristic of the saponification P204, not only are the extraction capacity, the utilization rate and the vanadium extraction rate increased, but also influences of iron, phosphorus and arsenic on V2O5 purity are effectively avoided, vanadium precipitation can be directly conducted after back extraction, a high-purity vanadium product is prepared, and the phenomenon that chlorine is released in the oxidization process to pollute the environment is avoided. The method has the advantages that the extraction stages and part of the processes are reduced, the technological process is simplified, the cost is reduced, the economic benefit is increased, and the double effects of making the best use of everything and protecting the environment are achieved.
公开/授权文献:
- CN107177737B 废钒催化剂综合回收利用方法 公开/授权日:2018-12-07
IPC结构图谱:
C | 化学;冶金 |
--C22 | 冶金(铁的冶金入C21);黑色或有色金属合金;合金或有色金属的处理 |
----C22B | 金属的生产或精炼;原材料的预处理 |
------C22B7/00 | 处理非矿石原材料(如废料)以生产有色金属或其化合物 |