![一种联产BIT和MBIT的方法](/CN/2017/1/92/images/201710464137.jpg)
基本信息:
- 专利标题: 一种联产BIT和MBIT的方法
- 申请号:CN201710464137.6 申请日:2017-06-19
- 公开(公告)号:CN107021936B 公开(公告)日:2019-05-24
- 发明人: 王勇 , 龚真固 , 杨红文 , 单忠峰 , 刚海涛 , 李龙 , 韩毅 , 窦宝睿
- 申请人: 大连百傲化学股份有限公司
- 申请人地址: 辽宁省大连市普湾新区松木岛化工园区沐百路18号
- 专利权人: 大连百傲化学股份有限公司
- 当前专利权人: 大连百傲化学股份有限公司
- 当前专利权人地址: 辽宁省大连市普湾新区松木岛化工园区沐百路18号
- 代理机构: 大连科技专利代理有限责任公司
- 代理人: 佟蕊
- 主分类号: C07D275/04
- IPC分类号: C07D275/04
The invention discloses a method for coproducing BIT (1,2-benzisothiazoline-3-ketone) and MBIT (2-methyl-1,2-benzisothiazoline-3-ketone). The method comprises the following steps: 1) performing hydrolytic cyclization reaction on o-methylthiocyanophenyl serving as a raw material, water and chlorine, filtering and salifying the reaction liquid after the reaction to obtain a BIT salt aqueous solution, acidizing and filtering to obtain a BIT product, and absorbing, pressurizing and condensing a byproduct methane chloride generated in the reaction process to collect for later use; 2) adding the BIT salt aqueous solution obtained in the step 1) into a high-pressure kettle, adding the byproduct methane chloride obtained in the step 1), and performing temperature-increasing reaction to obtain a mixture containing the MBIT and a byproduct MOBIT (3-methoxyl-1,2-benzisothiazoline); 3) adding the mixture containing the MBIT and the byproduct MOBIT and obtained in the step 2) into the hydrolytic cyclization reaction in the step 1), performing demethylating reaction on the byproduct MOBIT to change into BIT and methane chloride, combining the MBIT with hydrogen chloride to form MBIT hydrochloride, and performing separation steps such as filtering and neutralizing on the reaction mixture to obtain BIT and MBIT products separately. The method has the advantages of reasonable process, energy saving, low pollution, capability of greatly reducing production cost and the like.
公开/授权文献:
- CN107021936A 一种联产BIT和MBIT的方法 公开/授权日:2017-08-08
IPC结构图谱:
C | 化学;冶金 |
--C07 | 有机化学 |
----C07D | 杂环化合物 |
------C07D275/00 | 杂环化合物,含有1-2-噻唑或氢化1,2-噻唑环 |
--------C07D275/04 | .和碳环或碳环系稠合 |