The invention discloses a method for producing a printed circuit board by using calixarene. The method comprises the following steps of: a) adding the calixarene and an organic solvent into a container with a stirring device separately at normal pressure and temperature, and stirring the calixarene and the organic solvent continuously so as to obtain a calixarene solution; b) adding liquid copper slurry and the calixarene solution to a container with a dispersion device separately at normal pressure and temperature, performing dispersion continuously, filtering out the material so as to obtain a primary printing liquid; c) drilling and cleaning a substrate, and placing the substrate on a screen printing machine; d) applying the obtained primary printing liquid to the screen printing machine and applying the primary printing liquid to the substrate to form a printing liquid layer; and e) baking the obtained substrate in a baking oven and then naturally cooling the substrate so as to obtain the printed circuit board. The method for producing the printed circuit board by using calixarene is friendly to environment, can improve the adhesive force of copper particles on the substrate, and reduces the impedance of a conductive line.