The invention discloses a multiple access control method and control apparatus for a multi-hop acentric network. The method comprises the following steps: a wireless communication device controls switch control among a plurality of states by using a finite state machine; a time slot pre-stored variable array is set at the wireless communication device for storing the time slot information used by all nodes within the range of one hop of the wireless communication device; the wireless communication device adopts a superframe structure to transmit information during communication, wherein the superframe comprises a plurality of frame units, and each frame unit comprises a time slot information domain used for identifying time slot use and conflict information and a data domain used for transmitting service information; and the finite state machine controls the switch control of the wireless communication device between device conflict and device communication state according to the time slot information domain. According to the method, the distribution and conflict condition of the time slot is characterized by two bits, and the conflict can be solved within a superframe period. The occupancy of network resources is very low while the transmission delay is guaranteed, and moreover, the design frame format is compatible with the data format of the original message.