基本信息:
- 专利标题： 包含脒和取代的环戊二烯基配体的金属络合物
- 专利标题（英）：Metal complex comprising amidine and substituted cyclopentadienyl ligands
- 申请号：CN201580049929.6 申请日：2015-09-08
- 公开(公告)号：CN106687468A 公开(公告)日：2017-05-17
- 发明人： 彼得·卡鲍姆 , 理查德·托马斯·威廉姆·斯科特 , 约翰·范德莫斯迪克
- 申请人： 阿朗新科荷兰有限公司
- 申请人地址： 荷兰赫伦
- 专利权人： 阿朗新科荷兰有限公司
- 当前专利权人： 阿朗新科荷兰有限公司
- 当前专利权人地址： 荷兰赫伦
- 代理机构： 北京康信知识产权代理有限责任公司
- 代理人： 张英; 宫传芝
- 优先权： 14185359.8 20140918 EP
- 国际申请： PCT/EP2015/070498 2015.09.08
- 国际公布： WO2016/041818 EN 2016.03.24
- 进入国家日期： 2017-03-16
- 主分类号： C07F17/00
- IPC分类号： C07F17/00 ; C08F210/18 ; C08F10/02 ; C08F4/6592
A metal complex of the formula (1 ) CyLMZp(A)n (1 ), wherein M is a group 4 metal Z is an anionic ligand, p is number of 1 to 2, preferably 2, Cy is a cyclopentadienyl-type ligand substituted with at least one aliphatic C3-C20 hydrocarbyl group, which is bonded to the cyclopentadienyl-type ligand, in particular to its cyclopentadienyl ring, via a secondary, a tertiary or quaternary carbon atom and, L is an amidinate ligand of the formula (2), wherein the amidine-containing ligand is covalently bonded to the metal M via the imine nitrogen atom, and Sub1 is a substituent comprising a group 14 atom through which Sub1 is bonded to the imine carbon atom and Sub2 is a substituent comprising a heteroatom of group 15, through which Sub2 is bonded to the imine carbon atom and A is a neutral Lewis base ligand selected from the list consisting of ether, thioether, amine, tertiary phosphane, imine, nitrile and isonitrile,wherein the number of said metal ligands "n" is in the range of 0 to the amount that specifies the 18-electron rule.
公开/授权文献:
- CN106687468B 包含脒和取代的环戊二烯基配体的金属络合物 公开/授权日：2020-04-21