![一种硝基苯液相加氢制苯胺的方法](/CN/2015/1/131/images/201510656107.jpg)
基本信息:
- 专利标题: 一种硝基苯液相加氢制苯胺的方法
- 申请号:CN201510656107.6 申请日:2015-10-12
- 公开(公告)号:CN106565504B 公开(公告)日:2018-09-28
- 发明人: 金汉强 , 孙盛凯 , 李玉杰 , 杨忠林 , 丁红霞
- 申请人: 中国石油化工股份有限公司 , 南化集团研究院
- 申请人地址: 江苏省南京市六合区葛关路699号
- 专利权人: 中国石油化工股份有限公司,南化集团研究院
- 当前专利权人: 中国石油化工股份有限公司,中石化南京化工研究院有限公司
- 当前专利权人地址: 江苏省南京市六合区葛关路699号
- 代理机构: 南京天翼专利代理有限责任公司
- 代理人: 汤志武
- 主分类号: C07C211/46
- IPC分类号: C07C211/46 ; C07C209/36 ; B01J23/89
The invention discloses a method for preparing aniline through liquid-phase hydrogenation of nitrobenzene and belongs to the technical field of catalytic hydrogenation and organic synthesis. The method comprises the specific steps: adding a certain amount of a hydrogenation catalyst which is prepared through loading noble metal to carbon black as a carrier, and a solvent, i.e., aniline into a fluidized-bed hydrogenation reactor; and proportioning nitrobenzene and the aniline according to certain concentration, then, performing preheating to certain temperature, enabling the nitrobenzene and hydrogen gas to continuously enter the fluidized-bed hydrogenation reactor, and subjecting the nitrobenzene to a hydrogenation reaction under the catalysis of the noble-metal catalyst under the conditions of certain temperature, certain pressure and certain residence time, so as to produce the aniline and water. The conversion ratio of the nitrobenzene is higher than 99.99%, and the selectivity to the aniline is higher than 99.95%.
公开/授权文献:
- CN106565504A 一种硝基苯液相加氢制苯胺的方法 公开/授权日:2017-04-19
IPC结构图谱:
C | 化学;冶金 |
--C07 | 有机化学 |
----C07C | 无环或碳环化合物 |
------C07C211/00 | 含有与碳架连接的氨基的化合物 |
--------C07C211/01 | .与非环碳原子连接的氨基 |
----------C07C211/44 | ..有与仅有1个六元芳环连接的氨基 |
------------C07C211/45 | ...单胺 |
--------------C07C211/46 | ....苯胺 |