基本信息:
- 专利标题： 一种无金属加氢催化剂在催化苯加氢反应中的应用
- 专利标题（英）：Application of metal-free hydrogenation catalyst to catalysis of benzene hydrogenation
- 申请号：CN201610199080.7 申请日：2016-04-01
- 公开(公告)号：CN105837391A 公开(公告)日：2016-08-10
- 发明人： 郝芳 , 张文斌 , 刘平乐 , 熊伟 , 熊绍锋 , 罗和安
- 申请人： 湘潭大学
- 申请人地址： 湖南省湘潭市雨湖区羊牯塘27号
- 专利权人： 湘潭大学
- 当前专利权人： 湘潭大学
- 当前专利权人地址： 湖南省湘潭市雨湖区羊牯塘27号
- 代理机构： 湘潭市汇智专利事务所
- 代理人： 冷玉萍
- 主分类号： C07C13/18
- IPC分类号： C07C13/18 ; C07C13/20 ; C07C5/10 ; C07C5/11 ; B01J27/24
The invention discloses application of a metal-free hydrogenation catalyst to catalysis of benzene hydrogenation. The metal-free hydrogenation catalyst used in the invention is a nitrogen-doped carbon nanotube prepared by using an impregnation method with melamine as a nitrogen source or prepared by using an in-situ synthesis method with ammonia gas as the nitrogen source, and is applied to benzene hydrogenation. According to the invention, the nitrogen-doped carbon nanotube is used as the benzene hydrogenation catalyst, is not loaded with any metal active component and achieves the purpose of hydrogenation catalysis only through modification by nitrogen doping; usage of precious metals is avoided in the whole reaction process, so cost is saved, the environment is not polluted, and the catalyst is reusable; and the catalyst is simple to prepare, low in cost, good in hydrogenation effect, easily controllable in reactions and friendly to environment, does not cause secondary pollution to environment and can be widely applied to a variety of hydrogenation reactions.
公开/授权文献:
- CN105837391B 一种无金属加氢催化剂在催化苯加氢反应中的应用 公开/授权日：2017-12-08