The invention discloses a preparation method for a compound wear-resistant coating on the surface of a beryllium-copper alloy. The preparation method comprises the following steps: by adopting a double-layered glow plasma diffusion metallizing technology, preparing a diffusion coating layer on the surface of a beryllium-copper workpiece by taking a target material manufactured by any one wire of W, Mo and Nb or a W-Mo alloy, a Mo-Nb alloy, a W-Nb alloy and a W-Mo-Nb alloy and a beryllium-copper alloy panel as a source electrode, wherein before preparation, diamond particles subjected to Cu surface metallized treatment are uniformly sprayed to the surface of the beryllium-copper workpiece, so that the diamond particles are dispersively distributed; in the preparation process of the diffusion coating layer, uniformly spraying the diamond particles subjected to Cu surface metallized treatment to the surface of the workpiece once if the thickness of the coating is increased by 2-5[mu]m; after preparation of the diffusion coating layer is finished, introducing hydrogen for quick cooling; and then polishing the surface of the coating, and exposing the surfaces of the diamond particles. The coating prepared by the method has high electric conductivity, heat conductivity and wear resistance, the bonding strength of the coating with a matrix is high, and the preparation technology is simple in process.