
基本信息:
- 专利标题: 一种磷矿石的利用方法
- 专利标题(英):Utilization method of phosphate ores
- 申请号:CN201610054867.4 申请日:2016-01-27
- 公开(公告)号:CN105692575A 公开(公告)日:2016-06-22
- 发明人: 聂登攀 , 王振杰 , 刘安荣 , 薛安
- 申请人: 贵州省冶金化工研究所
- 申请人地址: 贵州省贵阳市宝山南路59号
- 专利权人: 贵州省冶金化工研究所
- 当前专利权人: 贵州省冶金化工研究所
- 当前专利权人地址: 贵州省贵阳市宝山南路59号
- 代理机构: 北京联创佳为专利事务所
- 代理人: 韩炜
- 主分类号: C01B25/32
- IPC分类号: C01B25/32 ; C01F11/46 ; C01B25/22 ; C01B25/46 ; C09K21/04
The invention discloses a utilization method of phosphate ores. The utilization method comprises the following steps: crushing and finely grinding the phosphate ores to obtain phosphate ore powder; stirring the phosphate ore powder and hydrochloric acid to react at a room temperature for 0.5 hour to 6 hours; carrying out solid-liquid separation; carrying out fluorine removal, impurity removal, calcium-phosphorus separation (sedimentation, filtering, extracting, drying and the like) on a liquid solution; furthermore, treating a residual calcium chloride solution; finally, obtaining products including fertilizer-grade calcium hydrogen phosphate, feed-grade calcium hydrogen phosphate, phosphorus-nitrogen composite flame retardant, tricalcium phosphate, calcium sulfate whiskers and the like, and also obtaining a diluted hydrochloric acid solution; rectifying and concentrating the diluted hydrochloric acid solution and returning the solution back to a phosphate ore powder acidolysis procedure. According to the utilization method, the used hydrochloric acid can be circularly utilized, and the hydrochloric acid can be generated; the obtained hydrochloric acid is used for decomposing the phosphate ores again and the acidolysis cost is low; meanwhile, the phosphorus chemical products including the fertilizer-grade calcium hydrogen phosphate, the feed-grade calcium hydrogen phosphate, the phosphorus-nitrogen composite flame retardant, the tricalcium phosphate, the calcium sulfate whiskers and the like can also be obtained, so that the comprehensive utilization efficiency of the phosphate ores is high and the economic benefits are good.
公开/授权文献:
- CN105692575B 一种磷矿石的利用方法 公开/授权日:2018-02-09
IPC结构图谱:
C | 化学;冶金 |
--C01 | 无机化学 |
----C01B | 非金属元素;其化合物 |
------C01B25/00 | 磷;其化合物 |
--------C01B25/16 | .磷的含氧酸;其盐类 |
----------C01B25/26 | ..磷酸盐 |
------------C01B25/32 | ...镁、钙、锶或钡的磷酸盐 |