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基本信息:
- 专利标题: 一种利用木屑合成航空煤油环烷烃和芳香组分的方法
- 申请号:CN201410592388.9 申请日:2014-10-28
- 公开(公告)号:CN105623702B 公开(公告)日:2018-04-10
- 发明人: 李全新 , 毕培燕 , 张雅静 , 汪继聪 , 姜沛汶 , 吴小平 , 薛鹤 , 刘俊旭
- 申请人: 中国科学技术大学
- 申请人地址: 安徽省合肥市包河区金寨路96号
- 专利权人: 中国科学技术大学
- 当前专利权人: 中国科学技术大学
- 当前专利权人地址: 安徽省合肥市包河区金寨路96号
- 代理机构: 北京科迪生专利代理有限责任公司
- 代理人: 杨学明; 孟卜娟
- 主分类号: C10G1/00
- IPC分类号: C10G1/00 ; C10G69/02
The invention provides a method for synthesizing aviation kerosene cycloparaffin and aroma components by the utilization of wood chips. The method comprises the following steps: Step 1, wood chips undergo catalytic cracking to obtain low-carbon aromatics: a catalyst is nickel/magnesium-containing modified NiO/MgO/Al-MCM-41, and low-carbon aromatics based on C6-C8 is formed after catalytic reaction of wood chips; Step 2, low-carbon aromatics is directionally converted to aromatics within the range of kerosene: an alkylating agent is low carbon olefins obtained after synchronous catalytic cracking of wood chips, a catalyst is a highly acidic xPF6-[bmim]-yAlCl3 (x,y=0.5-2) ionic liquid, and aromatics based on C9-C14 is formed after electrophilic substitution reaction of low-carbon aromatics; and Step 3, C9-C14 aromatics is directionally converted to cycloparaffin: a catalyst is palladium modified Pd/Al-MCM-22, and cycloparaffin based on C9-C14 is formed. Basic technical requirements of common aircraft fuel can be met. The method can be used for synthesizing aroma and cycloparaffin components in biological aviation kerosene.
公开/授权文献:
- CN105623702A 一种利用木屑合成航空煤油环烷烃和芳香组分的方法 公开/授权日:2016-06-01