![一种1-(3,4-二氯苯基)-2-硫脲的清洁生产方法](/CN/2015/1/179/images/201510897401.jpg)
基本信息:
- 专利标题: 一种1-(3,4-二氯苯基)-2-硫脲的清洁生产方法
- 专利标题(英):Clean production method of 1-(3,4-dichlorophenyl)-2-thiourea
- 申请号:CN201510897401.6 申请日:2015-12-08
- 公开(公告)号:CN105503678A 公开(公告)日:2016-04-20
- 发明人: 陈田木 , 彭炫 , 杨洋 , 陈宝兴 , 王海明
- 申请人: 江苏远征化工有限公司
- 申请人地址: 江苏省连云港市燕尾港临港产业区324省道西侧经九路东侧
- 专利权人: 江苏远征化工有限公司
- 当前专利权人: 江苏远征化工有限公司
- 当前专利权人地址: 江苏省连云港市燕尾港临港产业区324省道西侧经九路东侧
- 代理机构: 北京康思博达知识产权代理事务所
- 代理人: 汪送来
- 主分类号: C07C335/16
- IPC分类号: C07C335/16
The invention discloses a clean production method of 1-(3,4-dichlorophenyl)-2-thiourea. The clean production method comprises a step of treating production wastewater of 1-(3,4-dichlorophenyl)-2-thiourea, wherein the treatment step comprises the following steps that (1) the production wastewater of the 1-(3,4-dichlorophenyl)-2-thiourea is subjected to pH value regulation by ammonia, then, separation is performed to obtain 3,4-dichlorophenyl and separating liquid, and the 3,4-dichlorophenyl is reused in the production step of the 1-(3,4-dichlorophenyl)-2-thiourea; (2) the separating liquid in the first step is sequentially subjected to vacuum concentration, crystallization and separation to obtain condensed water, ammonium chloride and crystal mother liquor, and the condensed water and the crystal mother liquor are reused in the production step of the 1-(3,4-dichlorophenyl)-2-thiourea. The clean production method of the 1-(3,4-dichlorophenyl)-2-thiourea provided by the invention has the advantages that the total resource recycling of the production wastewater can be realized, and the yield of the 1-(3,4-dichlorophenyl)-2-thiourea is improved to higher than 97 percent.
IPC结构图谱:
C | 化学;冶金 |
--C07 | 有机化学 |
----C07C | 无环或碳环化合物 |
------C07C335/00 | 硫脲,即含下列基团NCSN或NCSN中的任何一个的化合物,其中的氮原子不属于硝基或亚硝基 |
--------C07C335/04 | .硫脲的衍生物 |
----------C07C335/16 | ..有硫脲基的氮原子连接在碳架的六元芳环的碳原子上 |