![一种低温筛选甲醇制烯烃催化剂的方法](/CN/2015/1/174/images/201510872910.jpg)
基本信息:
- 专利标题: 一种低温筛选甲醇制烯烃催化剂的方法
- 专利标题(英):Method for screening methanol-to-olefin catalyst at low temperature
- 申请号:CN201510872910.3 申请日:2015-12-02
- 公开(公告)号:CN105403477A 公开(公告)日:2016-03-16
- 发明人: 张福丽 , 常云峰
- 申请人: 天津众智科技有限公司
- 申请人地址: 天津市塘沽区经济技术开发区第十大街泰丰路99号
- 专利权人: 天津众智科技有限公司
- 当前专利权人: 天津众智科技有限公司
- 当前专利权人地址: 天津市塘沽区经济技术开发区第十大街泰丰路99号
- 代理机构: 山西五维专利事务所
- 代理人: 魏树巍
- 主分类号: G01N5/02
- IPC分类号: G01N5/02 ; C07C1/20 ; C07C11/04 ; C07C11/06
The invention discloses a method for screening methanol-to-olefin catalysts at low temperature, Catalyst powder is contained in a DVS instrument sample chamber, and the temperature of the sample chamber is kept 60 DEG C or below; the sample chamber is purged with inert gas, the ratio of dry air to wet air is controlled and regulated to be 98:2, the changing curve of the weight of the catalysts together with time is detected, an adsorption kinetics curve of the catalysts generated when the relative partial pressure of methanol steam is 2% is acquired, the partial pressure of the methanol steam in the inert gas is regulated by changing the ratio of dry air to wet air, changes of the weight of the catalysts are detected under different partial pressures, and an adsorption isotherm of the catalysts in the methanol steam in different concentration is acquired; the point with the maximum adsorption speed (maximum slope value) is searched for from the acquired adsorption isotherm, and the catalytic performance of the catalysts on an MTO reaction is judged. The method has the advantages of being easy to operate and high in accuracy rate when the average diolefin selectivity degree of the catalysts is judged.
公开/授权文献:
- CN105403477B 一种低温筛选甲醇制烯烃催化剂的方法 公开/授权日:2021-02-12
IPC结构图谱:
G | 物理 |
--G01 | 测量;测试 |
----G01N | 借助于测定材料的化学或物理性质来测试或分析材料 |
------G01N5/00 | 用称量的方法分析材料,例如称量从气体或液体分离出的微粒 |
--------G01N5/02 | .利用物质吸收或吸附某些组分并测定吸附剂的重量变化,例如测定含水量 |