基本信息:
- 专利标题： 石墨基掺铈β—PbO2电极的制备方法及其应用
- 专利标题（英）：Preparation method of graphite-based cerium-doped beta-PbO2 electrode and application of graphite-based cerium-doped beta-PbO2 electrode
- 申请号：CN201410145309.X 申请日：2014-04-11
- 公开(公告)号：CN104237342A 公开(公告)日：2014-12-24
- 发明人： 万平玉 , 莫恒亮 , 陈咏梅 , 王西志 , 毕海成 , 万平英 , 孙艳芝 , 唐阳 , 杨晓进
- 申请人： 北京化工大学
- 申请人地址： 北京市朝阳区北三环东路15号
- 专利权人： 北京化工大学
- 当前专利权人： 北京中立鸿环境技术有限公司
- 当前专利权人地址： 北京市朝阳区北三环东路15号
- 代理机构： 北京风雅颂专利代理有限公司
- 代理人： 李翔; 李弘
- 主分类号： G01N27/30
- IPC分类号： G01N27/30 ; G01N27/26
The invention discloses a preparation method of a graphite-based cerium-doped beta-PbO2 electrode and application of the graphite-based cerium-doped beta-PbO2 electrode. The graphite-based cerium-doped beta-PbO2 electrode is obtained by taking graphite as an anode and directly electroplating cerium-doped beta-PbO2 on graphite; components of electroplating liquid comprise 0.5-0.6mol/L of Pb(NO3)2, 0.2-0.8mol/L of Cu(NO3)2, 0.05-0.1mol/L of HNO3 and 0.002-0.008mol/L of Ce(NO3)3 and the balance being water; and in an electroplating process, the current density is 20-30MA/cm<2>, the temperature of the electroplating liquid is 70-85 DEG C and the electroplating time is 6-8 hours. According to the method, the production cost is low and the production process is simple; and a beta-PbO2 active layer with small grain sizes can be obtained by doping cerium into the electroplating liquid. The electrode is used as a working electrode to detect COD and can be used for rapidly, simply and accurately detecting the COD in water; and the detection efficiency can be effectively improved.
公开/授权文献:
- CN104237342B 石墨基掺铈β—PbO2电极的制备方法及其应用 公开/授权日：2017-01-04
IPC结构图谱:
| G | 物理 |
| --G01 | 测量；测试 |
| ----G01N | 借助于测定材料的化学或物理性质来测试或分析材料 |
| ------G01N27/00 | 用电、电化学或磁的方法测试或分析材料 |
| --------G01N27/02 | .通过测试阻抗 |
| ----------G01N27/28 | ..电解池部件 |
| ------------G01N27/30 | ...电极，例如测试电极；半电池 |