
基本信息:
- 专利标题: 一种3,4-二氯溴苯的制备方法
- 专利标题(英):Method for preparing 3,4-dichloro bromobenzene
- 申请号:CN201410133178.3 申请日:2014-04-04
- 公开(公告)号:CN103922892A 公开(公告)日:2014-07-16
- 发明人: 郑辉东 , 赵素英 , 吴丹 , 王碧玉
- 申请人: 福州大学
- 申请人地址: 福建省福州市闽侯县上街镇大学城学园路2号福州大学新区
- 专利权人: 福州大学
- 当前专利权人: 福建桦智工程技术有限公司
- 当前专利权人地址: 福建省福州市闽侯县上街镇大学城学园路2号福州大学新区
- 代理机构: 福州元创专利商标代理有限公司
- 代理人: 蔡学俊
- 主分类号: C07C25/02
- IPC分类号: C07C25/02 ; C07C17/12 ; C07C17/392
The invention belongs to the chemical engineering field, and particularly discloses a method for preparing 3,4-dichloro bromobenzene. The method comprises steps of adding reduced iron powder into the raw material o-dichlorobenzene, inletting bromine water under certain pressure and temperature, and carrying out bromination reaction in a bromination kettle; carrying out multistage crystallization on the crude bromized 3,4-dichloro bromobenzene through solution, so as to purify the 3,4-dichloro bromobenzene, wherein the crude bromized 3,4-dichloro bromobenzene is crystallized by at least one stage, generally by multiple stages, namely, from one stage to three stages, so that a complete cycle of crystallization and purification of the 3,4-dichloro bromobenzene product is formed. The method has the main beneficial effects that the product is not polluted by foreign solvents or other materials, for the byproduct 2,3- dichloro bromobenzene generated in preparation of 3,4-dichloro bromobenzene through o-dichlorobenzene is used as the solvent; particularly, reduction of the yield of 3,4-dichloro bromobenzene caused by intensified side reaction of the 2,3- dichloro bromobenzene due to rectification high temperature is avoided; the method has the characteristics of high yield of the product, high purity and high production efficiency.
公开/授权文献:
- CN103922892B 一种3,4-二氯溴苯的制备方法 公开/授权日:2015-12-02